Structural Stability Diagram of ALnP(2)S(6) Compounds (A = Na, K, Rb, Cs;Ln = Lanthanide)

Schoop, Leslie M.; Eger, Roland; Kremer, Reinhard K.; Kuhn, Alexander; Nuss, Jürgen und Lotsch, Bettina V. (2017): Structural Stability Diagram of ALnP(2)S(6) Compounds (A = Na, K, Rb, Cs;Ln = Lanthanide). In: Inorganic Chemistry, Bd. 56, Nr. 3: S. 1121-1131

Abstract

Thiophosphate compounds have been studied extensively in the past for their rich structural variations and for a large variety of interesting properties. Here, we report 11 new phases with the composition ALnP(2)S(6) (A = Na, K, Rb, Cs;Ln = lanthanide). These new thiophosphates crystallize in four different structure types, with the space groups Fdd2, P (1) over bar, P21, and P21/c, respectively. All phases are insulating and the calculated band gaps range between 3 eV and 3.5 eV. Magnetic measurements on the compounds with open f-shells show paramagnetic behavior and magnetic moments that match the expected free ion values of the respective lanthanide cations. We present a structural stability phase diagram for the ALnP(2)S(6) family of compounds, which reveals a clear relationship between ionic radii and the preferred crystal structure, as well as stability regions to form ALnP(2)S(6)-type phases.

• Dokumententyp: Zeitschriftenartikel
• Fakultät: Chemie und Pharmazie > Department Chemie
• Themengebiete: 500 Naturwissenschaften und Mathematik > 540 Chemie
• ISSN: 0020-1669
• Sprache: Englisch