
Abstract
Starting from [q5-C5Br5]M n(CO),, the first r-complex of a cyclopentadienyl ligand with five silyl substituents, [q 5-C5(SiMe2H)5M] n(CO),, was prepared by a series of halogen-lithium exchange reactions, followed by silylation with SiMe2HCI. The crystal structure determination of this compound shows a highly symmetrical "paddle wheel" orientation of the five silyl groups around the cyclopentadienyl ring.
Item Type: | Journal article |
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Faculties: | Chemistry and Pharmacy |
Subjects: | 500 Science > 540 Chemistry |
URN: | urn:nbn:de:bvb:19-epub-5428-3 |
Item ID: | 5428 |
Date Deposited: | 06. Aug 2008, 12:14 |
Last Modified: | 04. Nov 2020, 12:48 |