Chemoselective Reduction: Xanthates as Traceless Precursors of Polyfunctionalized alpha,alpha-Dichloroketones

Anthore-Dalion, Lucile und Zard, Samir Z. (2017): Chemoselective Reduction: Xanthates as Traceless Precursors of Polyfunctionalized alpha,alpha-Dichloroketones. In: Organic Letters, Bd. 19, Nr. 20: S. 5545-5548

Abstract

The use of BEt3 center dot H2O has allowed the chemoselective reductive dexanthylation in the presence of the very fragile alpha,alpha-dichloroketone motif. This has solved a major hurdle in our approach to this important, but hitherto grossly understudied, family of compounds and opened access to a number of very useful synthetic transformations.

• Dokumententyp: Zeitschriftenartikel
• Fakultät: Chemie und Pharmazie > Department Chemie
• Themengebiete: 500 Naturwissenschaften und Mathematik > 540 Chemie
• ISSN: 1523-7060
• Sprache: Englisch