Abstract
The preparation of protonated methanesulfonamide was carried out using the superacidic systems HF/AsF5 and HF/SbF5. The vibrational spectroscopic characterization was supported by quantum chemical calculations performed with the PBE1PBE method using the 6-311G++(3df, 3pd) basis set. A remarkable long nitrogen-sulfur bond length of 1.804(6) angstrom was observed in a single-crystal X-ray structure analysis of [CH3SO2NH3](+)[Sb2F11](-). It crystallizes in the orthorhombic space group P2(1)/c with four formula units in the unit cell. Furthermore the crystal structure of CH3SO2NH2 was revisited.
| Item Type: | Journal article |
|---|---|
| Faculties: | Chemistry and Pharmacy > Department of Chemistry |
| Subjects: | 500 Science > 540 Chemistry |
| ISSN: | 0044-2313 |
| Language: | English |
| Item ID: | 54281 |
| Date Deposited: | 14. Jun 2018, 09:55 |
| Last Modified: | 04. Nov 2020, 13:33 |
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