Abstract
(S)-alpha-Phenylethylamine was used in the microwave-assisted Kabachnik-Fields condensation with paraformaldehyde and > P(O)H species, such as dialkyl phosphites, ethyl phenyl-H-phosphinate and diphenylphosphine oxide to provide optically active alpha-aminophosphonates, alpha-aminophosphinate and alpha-aminophosphine oxide, or using a two equivalent quantity of paraformaldehyde and (RO)(2)P(O)H or Ph2P(O)H, bis(phosphonomethyl)amines and bis(phosphinoylmethyl)amine, respectively. The bis(phosphinoylmethyl)amine served as a precursor for an optically active bidentate P-ligand in the synthesis of a chiral platinum complex.
Item Type: | Journal article |
---|---|
Faculties: | Chemistry and Pharmacy > Department of Chemistry |
Subjects: | 500 Science > 540 Chemistry |
ISSN: | 0040-4020 |
Language: | English |
Item ID: | 54298 |
Date Deposited: | 14. Jun 2018, 09:55 |
Last Modified: | 04. Nov 2020, 13:33 |