Kohlenwasserstoffverbrückte Komplexe, XXV

Wieser, Michael; Sünkel, Karlheinz; Robl, Christian and Beck, Wolfgang (1992): Kohlenwasserstoffverbrückte Komplexe, XXV. C-C-Kupplung von anionischen Tricarbonylmangan-Komplexen cyclischer Polyene mit kationischen Tropylium-Metallverbindungen; Darstellung und Struktur von (OC)3Mn(-5:6-C7H8-C7H7)M(CO)3, (OC)3Mn(-5:6-C8H10-C7H7)M(CO)3 und (OC)3Mn(-5:6-C8H8-C7H7)M(CO)3(M = Cr, Mo, W). In: Chemische Berichte, Vol. 125, No. 6: pp. 1369-1373

Abstract

Hydrocarbon-Bridged Complexes, XXV. - C-C Coupling of Anionic Tricarbonyl Manganese Complexes of Cyclic Polyenes with Cationic Tropylium Metal Compounds; Preparation and Structure of (OC)3Mn(-5:6-C7H8-C7H7)M(CO)3, (OC)3Mn(-5:6-C8H10-C7H7)M(CO)3, and (OC)3Mn(-5:5-C8H8-C7H7)M(CO)3 (M = Cr, Mo, W)[Note ] The addition of the anionic complexes [(4-C7H8)Mn(CO)3]-, [(4-C8H10)Mn(CO)3]- and [(4-C8H8)Mn(CO)3]- to the cations [(7-C7H7)M(CO)3]+ (M = Cr, Mo, W) gives the hydrocarbon-bridged complexes (OC)3Mn(-5:6-C7H8-C7H7)M(CO)3, (OC)3Mn(-5:6-C8H10-C7H7)M(CO)3, and (OC)3Mn(-5:6-C8H8-C7H7)M(CO)3 (M = Cr, Mo, W). The structures of 4b and 6a have been determined by X-ray diffraction.

• Item Type: Journal article
• Faculties: Chemistry and Pharmacy
• Subjects: 500 Science > 540 Chemistry
• Signature: Chem. 26 h-125,5/8