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Neudert, Lukas; Heinke, Frank; Bräuniger, Thomas; Pucher, Florian J.; Vaughan, Gavin B.; Öckler, Oliver; Schnick, Wolfgang ORCID: 0000-0003-4571-8035 (2017): An unusual nitride network of aluminum-centered octahedra and phosphorus-centered tetrahedra and structure determination from microcrystalline samples. In: Chemical Communications, Vol. 53, No. 18: pp. 2709-2712
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A new imidooxonitridophosphate AlP(6)O(3)x(NH)(3-3x)N-9 with x approximate to 0.33 was synthesized under high-pressure high-temperature conditions. The crystal structure determination of the microcrystalline product involved a combination of electron microscopy, synchrotron X-ray diffraction and solid-state NMR. In the solid there are discrete AlN6 octahedra that interconnect imidophosphate layers. The network topology is unprecedented but is related to other nitride structures.