Organometallic Lewis Acids, Part LXI.([1]) Cationic Pentacarbonylrhenium Complexes [( OC)₅Re-L]⁺BF₄- with Aromatic Amines (L) as Ligands

Fritz, Peter M. und Beck, Wolfgang (2017): Organometallic Lewis Acids, Part LXI.([1]) Cationic Pentacarbonylrhenium Complexes [( OC)₅Re-L]⁺BF₄- with Aromatic Amines (L) as Ligands. In: Zeitschrift für Anorganische und Allgemeine Chemie, Bd. 643, Nr. 3: S. 225-227

Abstract

Aromatic amines (aniline and derivatives) react with (OC)(5)ReFBF3 to give the cationic complexes [(OC)(5)Re-L](+) as BF4- salts under mild conditions and in high yields. Dinuclear, dicationic complexes are formed with o- and p-phenylenediamine. Substitution of tetrafluoroborate by the N-donors is preferred before attack at a carbonyl ligand.

• Dokumententyp: Zeitschriftenartikel
• Fakultät: Chemie und Pharmazie > Department Chemie
• Themengebiete: 500 Naturwissenschaften und Mathematik > 540 Chemie
• ISSN: 0044-2313
• Sprache: Englisch