Fritz, Peter M.; Beck, Wolfgang (2017): Organometallic Lewis Acids, Part LXI.([1]) Cationic Pentacarbonylrhenium Complexes [( OC)₅Re-L]⁺BF₄- with Aromatic Amines (L) as Ligands. In: Zeitschrift für Anorganische und Allgemeine Chemie, Vol. 643, No. 3: pp. 225-227 |
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Abstract
Aromatic amines (aniline and derivatives) react with (OC)(5)ReFBF3 to give the cationic complexes [(OC)(5)Re-L](+) as BF4- salts under mild conditions and in high yields. Dinuclear, dicationic complexes are formed with o- and p-phenylenediamine. Substitution of tetrafluoroborate by the N-donors is preferred before attack at a carbonyl ligand.
Item Type: | Journal article |
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Faculties: | Chemistry and Pharmacy > Department of Chemistry |
Subjects: | 500 Science > 540 Chemistry |
ISSN: | 0044-2313 |
Language: | English |
ID Code: | 55830 |
Deposited On: | 14. Jun 2018 10:00 |
Last Modified: | 14. Jun 2018 10:00 |
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