Organometallic Lewis Acids, Part LXI.([1]) Cationic Pentacarbonylrhenium Complexes [( OC)₅Re-L]⁺BF₄- with Aromatic Amines (L) as Ligands

Fritz, Peter M. and Beck, Wolfgang (2017): Organometallic Lewis Acids, Part LXI.([1]) Cationic Pentacarbonylrhenium Complexes [( OC)₅Re-L]⁺BF₄- with Aromatic Amines (L) as Ligands. In: Zeitschrift für Anorganische und Allgemeine Chemie, Vol. 643, No. 3: pp. 225-227

Abstract

Aromatic amines (aniline and derivatives) react with (OC)(5)ReFBF3 to give the cationic complexes [(OC)(5)Re-L](+) as BF4- salts under mild conditions and in high yields. Dinuclear, dicationic complexes are formed with o- and p-phenylenediamine. Substitution of tetrafluoroborate by the N-donors is preferred before attack at a carbonyl ligand.

• Item Type: Journal article
• Faculties: Chemistry and Pharmacy > Department of Chemistry
• Subjects: 500 Science > 540 Chemistry
• ISSN: 0044-2313
• Language: English