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Dong, Zhi-Bing; Balkenhohl, Moritz; Tan, Eric; Knochel, Paul (2018): Synthesis of Functionalized Diaryl Sulfides by Cobalt-Catalyzed Coupling between Arylzinc Pivalates and Diaryl Disulfides. In: Organic Letters, Vol. 20, No. 23: pp. 7581-7584
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Abstract

An efficient protocol for the cobalt-catalyzed preparation of diaryl sulfides from solid organozinc pivalates and commercially available diaryl disulfides is reported. This cross-coupling proceeds at room temperature and displays a good functional group tolerance, allowing the preparation of a diversity of symmetrical or asymmetrical diaryl sulfides in 60-95% yield.