Wavepacket Splitting in the First 100 fs Determines the Products from the Bond Cleavage of Diphenylmethylchloride

Sailer, Christian F.; Krebs, N.; Fingerhut, Benjamin P.; Vivie-Riedle, Regina de und Riedle, Eberhard (2013): Wavepacket Splitting in the First 100 fs Determines the Products from the Bond Cleavage of Diphenylmethylchloride. In: EPJ Web of Conferences, Bd. 41, Nr. 05042

Abstract

An elementary chemical reaction proceeds through two distinct conical intersections. Benzhydryl radicals are formed with a delay of 80 fs, cations after 125 fs. The optical signal increases more slowly due to planarization and solvation.

• Dokumententyp: Zeitschriftenartikel
• Fakultät: Physik
• Themengebiete: 500 Naturwissenschaften und Mathematik > 530 Physik
• ISSN: 2100-014X
• Sprache: Englisch