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Sailer, Christian F.; Krebs, N.; Fingerhut, Benjamin P.; Vivie-Riedle, Regina de; Riedle, Eberhard ORCID: 0000-0002-2672-5718 (2013): Wavepacket Splitting in the First 100 fs Determines the Products from the Bond Cleavage of Diphenylmethylchloride. In: EPJ Web of Conferences, Vol. 41, No. 05042
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Abstract

An elementary chemical reaction proceeds through two distinct conical intersections. Benzhydryl radicals are formed with a delay of 80 fs, cations after 125 fs. The optical signal increases more slowly due to planarization and solvation.