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Pugliesi, Igor; Langhals, Heinz ORCID: 0000-0002-8038-4547; Riedle, Eberhard ORCID: 0000-0002-2672-5718 (May 2011): Förster resonant energy transfer (FRET) in orthogonal chromophores. 2011 Conference on Lasers and Electro-Optics Europe and 12th European Quantum Electronics Conference (CLEO EUROPE/EQEC), 22-26 May 2011, Munich, Germany.
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Abstract

The authors investigate the very principles of FRET on a set of perylene bisimide dyads by pump-probe spectroscopy, chemical variation and calculations. These dyads undergo transfer with near unit quantum efficiency although the transition dipole moments of donor and acceptor are in a perfectly orthogonal arrangement to each other in the equilibrium geometry.