The First Picoseconds in the Life of Benzhydryl Cations: Ultrafast Generation and Chemical Reactions

Sailer, Christian F.; Fingerhut, Benjamin P.; Ammer, Johannes; Nolte, Christoph; Pugliesi, Igor; Mayr, Herbert; Vivie-Riedle, Regina de und Riedle, Eberhard (2010): The First Picoseconds in the Life of Benzhydryl Cations: Ultrafast Generation and Chemical Reactions. International Conference on Ultrafast Phenomena, Snowmass, Colorado, United States, 18–23 July 2010. Technical Digest. Optical Society of America.

Abstract

For benzhydryl chloride compounds we observe that photodissociation only leads to radical pairs. The typically observed cations are formed by subsequent electron transfer. Reactions of cations in neat alcohols can then occur within 2.6 ps.

• Dokumententyp: Konferenzbeitrag (Paper)
• Fakultät: Physik
• Themengebiete: 500 Naturwissenschaften und Mathematik > 530 Physik
• Sprache: Englisch