Switching dynamics of the photochromic 1,1-dicyano-2-(4-cyanophenyl)-1,8a-dihydroazulene probed by sub-30 fs spectroscopy

Waele, Vincent de; Beutter, M.; Schmidhammer, Uli; Riedle, Eberhard und Daub, J. (Juni 2004): Switching dynamics of the photochromic 1,1-dicyano-2-(4-cyanophenyl)-1,8a-dihydroazulene probed by sub-30 fs spectroscopy. In: Chemical Physics Letters, Bd. 390, Nr. 4-6: S. 328-334

Abstract

We report the first time resolved investigation of the ring opening dynamics of the 1,1-dicyano-2-(4-cyanophenyl)-1,8a-dihydroazulene (CN-DHA) towards its vinylheptafulvene (CN-VHF) isomer. The kinetics are measured by sub-30 fs transient absorption spectroscopy for numerous probe wavelengths from 485 to 690 nm. The ring opening takes place within 1.2 ps on the CN-DHA-VHF S-1 potential energy surface. It is followed by the internal conversion from CN-VHF-S-1 to CN-VHF-S-0 in 13 ps. We observe coherent oscillations of low frequency modes (150, 190, 330 and 500 cm(-1)) that are closely associated with the skeleton motions driving the CN-DHA structural changes immediately after the 30 fs UV excitation.

• Dokumententyp: Zeitschriftenartikel
• Fakultät: Physik
• Themengebiete: 500 Naturwissenschaften und Mathematik > 530 Physik
• ISSN: 0009-2614
• Sprache: Englisch