Palladium(II) Incorporation in the All‐Inorganic Cryptand [As4W40O140]28–: Synthesis and Structural Characterization of [Pd2Na2KAs4W40O140(H2O)]21–

Lin, Zhengguo; Izarova, Natalya V.; Mehari, Fitsumbirhan T. and Kortz, Ulrich (2018): Palladium(II) Incorporation in the All‐Inorganic Cryptand [As4W40O140]28–: Synthesis and Structural Characterization of [Pd2Na2KAs4W40O140(H2O)]21–. In: Zeitschrift für Anorganische und Allgemeine Chemie, Vol. 644, No. 22: pp. 1379-1382

Abstract

The palladium(II)-containing 40-tungsto-4-arsenate(III) [Pd2Na2KAs4W40O140(H2O)](21-) (1a) was synthesized by reaction of PdSO4 with the cryptate heteropolyanion [As4W40O140](28-) in potassium acetate buffer. The title compound was characterized by single-crystal XRD, IR, TGA, and elemental analysis.

• Item Type: Journal article
• Faculties: Medicine
• Subjects: 600 Technology > 610 Medicine and health
• ISSN: 0044-2313
• Language: English