Melamine-functionalized graphene oxide: Synthesis, characterization and considering as pseudocapacitor electrode material with intermixed POAP polymer

Ajdari, Farshad Boorboor; Kowsari, Elaheh; Ehsani, Ali; Chepyga, Liudmyla; Schirowski, Milan; Jäger, Sebastian; Kasian, Olga; Hauke, Frank and Ameri, Tayebeh (2018): Melamine-functionalized graphene oxide: Synthesis, characterization and considering as pseudocapacitor electrode material with intermixed POAP polymer. In: Applied Surface Science, Vol. 459: pp. 874-883

Abstract

In this study, Melamine functionalized graphene oxide (FGO-Melamine) was synthesized by chemical route. The prepared functionalized graphene oxide was characterized by different analytical techniques such as FT-IR, Raman spectroscopy, thermogravimetry coupled with mass spectrometry (TG-MS), X-Ray diffraction (XRD), field-emission scanning electron microscopy (FE-SEM), and X-ray photoelectron spectroscopy (XPS). To improve electrochemical properties of polyorthoaminophenol (POAP), the electropolymerized POAP/FGO-Melamine films, employed as an active electrode regarding electrochemical performance. In terms of electrochemical measurements, galvanostatic charge-discharge evaluation, EIS (electrochemical impedance spectroscopy) and CV (cyclic voltammetry) were employed for conducing an enquiry into supercapacitive performance of nanocomposite of POAP/FGO-Melamine. This graphene-based electrode showed a specific capacitance (SC) by 273 F g(-1) and high energy of 37.91 W kg(-1) at power density of 500 W kg(-1). The novel materials synthesized in the current work show higher efficiency compared to the carbon-based ones concerning redox reactions of capacitors consisting of good stability in the existence of aqueous electrolyte, large active surface area and ease synthesis method.

• Item Type: Journal article
• Faculties: Chemistry and Pharmacy > Department of Chemistry
• Subjects: 500 Science > 540 Chemistry
• ISSN: 0169-4332
• Language: English