Abstract
Treatment of THF solutions containing the rhodium(II) complex trans-[RhCl2(Mu(2)Ph)(2)] (1) with [Fe-2(Co)(9)] in the same solvent resulted in the formation of the Vaska-type complex trans-[RhCl(CO)((PBu2Ph)-Bu-t)(2)] (2) in high yield. The title complex 2 was obtained as pale yellow crystals, characterized by NMR and IR spectroscopy, as well as by microanalyses. Additionally, the molecular structure of 2 has been established by X-ray crystallography. As often reported for similar constituted compounds, the chlorido and carbonyl ligands in crystals of 2 are strongly disordered.
| Dokumententyp: | Zeitschriftenartikel |
|---|---|
| Fakultät: | Chemie und Pharmazie > Department Chemie |
| Themengebiete: | 500 Naturwissenschaften und Mathematik > 540 Chemie |
| ISSN: | 0932-0776 |
| Sprache: | Englisch |
| Dokumenten ID: | 67373 |
| Datum der Veröffentlichung auf Open Access LMU: | 19. Jul. 2019, 12:22 |
| Letzte Änderungen: | 04. Nov. 2020, 13:49 |
- Dokument bearbeiten
