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Balkenhohl, Moritz and Knochel, Paul ORCID logoORCID: https://orcid.org/0000-0001-7913-4332 (2018): Regioselective C-H Activation of Substituted Pyridines and other Azines using Mg- and Zn-TMP-Bases. In: Synopen, Vol. 2, No. 1: pp. 78-95 [PDF, 2MB]

Abstract

The metalation of substituted pyridines, diazines and related N-heterocycles using TMPMgCl center dot LiCl, TMP2Mg center dot 2LiCl, TMPZnCl center dot LiCl or TMP2Zn center dot 2LiCl(2) center dot 2MgCl(2) (TMP = 2,2,6,6-tetramethylpiperidyl) in the presence or absence of a Lewis acid is reviewed.

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