Rosellin A and B, two red diketopiperazine alkaloids from the mushroom Mycena rosella

Lohmann, Julia S.; Nussbaum, Monika von; Brandt, Wolfgang; Muelbradt, Julia; Steglich, Wolfgang und Spiteller, Peter (2018): Rosellin A and B, two red diketopiperazine alkaloids from the mushroom Mycena rosella. In: Tetrahedron, Bd. 74, Nr. 38: S. 5113-5118

Abstract

Rosellin A and B, two red diketopiperazine alkaloids with unprecedented structures, have been isolated from the fruiting bodies of the mushroom Mycena rosella. The structures of the rosellins were mainly deduced from their 2D NMR and HRMS (ESI) spectra. Their absolute configuration was determined by comparison of the CD spectra of the rosellins with the corresponding CD spectra obtained by quantum chemical calculations. Root exposure to rosellin A led to bleaching of the leaves of Lepidium sativum plants.

• Dokumententyp: Zeitschriftenartikel
• Fakultät: Chemie und Pharmazie > Department Chemie
• Themengebiete: 500 Naturwissenschaften und Mathematik > 540 Chemie
• ISSN: 0040-4020
• Sprache: Englisch