Abstract
Photoinduced linkage isomers (PLIs) of NO and NO2- are selectively generated by an appropriate choice of irradiation wavelength at low temperature within the same molecular complex [Rh(NO)(NO2)(2)((Bu2PH)-P-t)(2)]. The structures of the PLIs are characterised by photocrystallography and the corresponding vibrational changes by infrared spectroscopy. Using red light about 37% of the ON isonitrosyl PLI can be produced while irradiation with blue light produces about 80% of the (O,O) chelating NO2- isomer. Upon heating the NO2- PLI undergoes several structural transformations, which are characterised by infrared spectroscopy.
Item Type: | Journal article |
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Faculties: | Chemistry and Pharmacy > Department of Chemistry |
Subjects: | 500 Science > 540 Chemistry |
ISSN: | 1466-8033 |
Language: | English |
Item ID: | 67515 |
Date Deposited: | 19. Jul 2019, 12:22 |
Last Modified: | 04. Nov 2020, 13:49 |