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Eisold, Michael; Miiller-Deku, Adrian; Reiners, Felix; Didier, Dorian (2018): Parallel Approaches for the Functionalization of Thietes: alpha-Metalation versus C-H Activation. In: Organic Letters, Vol. 20, No. 15: pp. 4654-4658
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Abstract

For the first time, an approach to 3,4disubstituted thietes was developed through two complementary paths. While the first one relies on alpha-metalation, the second is based on direct C-H functionalization. A new library of sophisticated sulfur-containing four-membered rings is described, paving the way to new bioactive analogues and small heterocycle incorporation.