Thiete Dioxides as Templates Towards Twisted Scaffolds and Macrocyclic Structures

Baumann, Andreas N.; Reiners, Felix; Siegle, Alexander F. and Mayer, Peter (2020): Thiete Dioxides as Templates Towards Twisted Scaffolds and Macrocyclic Structures. Prof. Dr. Oliver Trapp Dr. Dorian Didier. In: Chemistry—A European Journal, Vol. 26, No. 27: pp. 6029-6035

Abstract

Thiete dioxide units have been employed as a template for further functionalization through C−H activation strategies. Using simple thiete dioxide building blocks, a new library of axially chiral molecules has been synthesized that owe their stability to electrostatic interactions in the solid state. Similar starting materials were further engaged in the formation of cyclic trimeric structures, opening the pathway to unprecedented macrocyclic ring systems.

• Item Type: Journal article
• Faculties: Chemistry and Pharmacy > Department of Chemistry
• Subjects: 500 Science > 540 Chemistry
• ISSN: 1521-3765
• Language: English