Cluster Expansions with Renormalized Activities and Applications to Colloids

Jansen, Sabine und Tsagkarogiannis, Dimitrios (2019): Cluster Expansions with Renormalized Activities and Applications to Colloids. In: Annales Henri Poincare, Bd. 21, Nr. 1: S. 45-79

Abstract

We consider a binary system of small and large objects in the continuous space interacting via a nonnegative potential. By integrating over the small objects, the effective interaction between the large ones becomes multi-body. We prove convergence of the cluster expansion for the grand canonical ensemble of the effective system of large objects. To perform the combinatorial estimate of hypergraphs (due to the multi-body origin of the interaction), we exploit the underlying structure of the original binary system. Moreover, we obtain a sufficient condition for convergence which involves the surface of the large objects rather than their volume. This amounts to a significant improvement in comparison to a direct application of the known cluster expansion theorems. Our result is valid for the particular case of hard spheres (colloids) for which we rigorously treat the depletion interaction.

• Dokumententyp: Zeitschriftenartikel
• Fakultät: Mathematik, Informatik und Statistik > Mathematik
• Themengebiete: 500 Naturwissenschaften und Mathematik > 510 Mathematik
• ISSN: 1424-0637
• Sprache: Englisch