Novel Cu(I) complexes of functionalized phosphines

Linert, S.; Wagner, S.; Schmidt, P.; Higham, L.; Hepples, C.; Waddell, P. and Karaghiosoff, K. (2019): Novel Cu(I) complexes of functionalized phosphines. In: Phosphorus Sulfur and Silicon and the Related Elements, Vol. 194, No. 4-6: pp. 565-568

Abstract

Novel tertiary phosphines R'PR2 with additional functionalities in the substituent R have been designed and prepared according to literature procedures. The coordination behavior of the additional functionality in the organic moiety and the phosphorus atom towards different Cu(I) salts was investigated. These reactions resulted in polynuclear complexes with unexpected structures involving Cu(I) atoms with different coordination numbers in the same compound. [GRAPHICS] .

• Item Type: Journal article
• Faculties: Chemistry and Pharmacy > Department of Chemistry
• Subjects: 500 Science > 540 Chemistry
• ISSN: 1042-6507
• Language: English