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Li, Jie und Knochel, Paul (2019): Chromium-Catalyzed Cross-Couplings and Related Reactions. In: Synthesis-Stuttgart, Vol. 51, No. 10: pp. 2100-2106

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Abstract

Transition-metal-catalyzed cross-couplings have been recognized as a powerful tool for sustainable syntheses. Despite the fact that remarkable progress was achieved by palladium and nickel catalysis, the high price and toxicity still remained a drawback. Recently, naturally more abundant and less toxic low-valent chromium salts, such as Cr(II) and Cr(III) chlorides, displayed notable unique catalytic reactivity. Thus, recent progress in the field of chromium-catalyzed cross-couplings and related reactions are highlighted in the present short review until December 2018.

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