Synthesis and molecular structure of [Rh(eta(5)-C5H5)(coe)(PtBu2H)] (coe = cis-cyclooctene)

Böttcher, Hans-Christian; Mayer, Peter und Beck, Daniel (2019): Synthesis and molecular structure of [Rh(eta(5)-C5H5)(coe)(PtBu2H)] (coe = cis-cyclooctene). In: Zeitschrift für Naturforschung Section B-A Journal of Chemical Sciences, Bd. 74, Nr. 5: S. 455-457

Abstract

The synthesis and structural characterization of the new olefinic complex [Rh(eta(5)-C5H5)(coe)(PtBu2H)] (2, coe = cis-cyclooctene) is reported. The title compound was easily prepared in good yield by a thermolytic approach using [Rh(eta(5)-C5H5)(coe)(2)] (1) and the secondary phosphane in toluene under reflux conditions. The compound 2 has been characterized by NMR spectroscopy and microanalysis. Single crystals of 2 were grown from n-hexane and the molecular structure has been established by X-ray diffraction.

• Dokumententyp: Zeitschriftenartikel
• Fakultät: Chemie und Pharmazie > Department Chemie
• Themengebiete: 500 Naturwissenschaften und Mathematik > 540 Chemie
• ISSN: 0932-0776
• Sprache: Englisch