Oxidized Hemithioindigo Photoswitches-Influence of Oxidation State on (Photo)physical and Photochemical Properties

Koettner, Laura; Schildhauer, Monika; Wiedbrauk, Sandra; Mayer, Peter und Dube, Henry (2020): Oxidized Hemithioindigo Photoswitches-Influence of Oxidation State on (Photo)physical and Photochemical Properties. In: Chemistry-A European Journal, Bd. 26, Nr. 47: S. 10712-10718

Abstract

The photophysical and photochemical properties of sulfoxide and sulfone derivatives of hemithioindigo photoswitches are scrutinized and compared to the unoxidized parent chromophores. Oxidation results in significantly blue-shifted absorptions and mostly reduction of photochromism while thermal stabilities of individual isomers remain largely unaltered. Effective photoswitching takes place at shorter wavelengths compared to parent hemithioindigos and high isomeric yields can be obtained reversibly in the respective photostationary states. Reversible solid-state photoswitching is observed for a twisted sulfone derivative accompanied by visible color changes. These results establish oxidized hemithioindigo photoswitches as promising and versatile tools for robust light-control of molecular behavior for a wide range of applications.

• Dokumententyp: Zeitschriftenartikel
• Fakultät: Chemie und Pharmazie > Department Chemie
• Themengebiete: 500 Naturwissenschaften und Mathematik > 540 Chemie
• ISSN: 0947-6539
• Sprache: Englisch