A Fast and Reliable Screening Setup for Homogeneous Catalysis with Gaseous Reactants at Extreme Temperatures and Pressures

Siebert, Max; Storch, Golo und Trapp, Oliver (2020): A Fast and Reliable Screening Setup for Homogeneous Catalysis with Gaseous Reactants at Extreme Temperatures and Pressures. In: Organic Process Research & Development, Bd. 24, Nr. 7: S. 1304-1309

Abstract

Modern catalysis research strongly focusses on optimizing multiple reaction parameters en route to find optimal conditions. However, a very limited number of fundamental parameter combinations, such as inert conditions, gaseous reactants, variable temperature, and elevated pressure, can be screened in a convenient and straightforward manner. We report a ready-to-use reaction setup that is designed for screening reactions with gaseous reactants under inert conditions in standard NMR tubes (0.5 mL) using temperatures between -40 and +100 degrees C and extreme pressures. Proof-of-concept reaction examples are discussed, and the coupling to modern analytic techniques including in situ IR spectroscopy is possible.

• Dokumententyp: Zeitschriftenartikel
• Fakultät: Chemie und Pharmazie > Department Chemie
• Themengebiete: 500 Naturwissenschaften und Mathematik > 540 Chemie
• ISSN: 1083-6160
• Sprache: Englisch