A Three-Step Synthesis of 1,7-Diazaperylene and Derivatives

Langhals, Heinz; Reichherzer, Susanne; Mayer, Peter und Polborn, Kurt (2020): A Three-Step Synthesis of 1,7-Diazaperylene and Derivatives. In: Synthesis-Stuttgart, Bd. 53, Nr. 04: S. 713-722

Abstract

1,7-Diazaperylene and various derivatives were synthesised in an upscaleable route from 1,5-diaminoanthraquinone and its Meerwein reaction with acrylonitrile and subsequent cyclisation with ammonia. The application of tert-butyl alcohol as the solvent led to a significant improvement in the Meerwein reaction.

• Dokumententyp: Zeitschriftenartikel
• Fakultät: Chemie und Pharmazie > Department Chemie
• Themengebiete: 500 Naturwissenschaften und Mathematik > 540 Chemie
• ISSN: 0039-7881
• Sprache: Englisch