Copper(I) and silver(I) complexes of bridging bis(quinaldinyl)phenylphosphine oxide ligand

Kirst, Christin und Karaghiosoff, Konstantin (2020): Copper(I) and silver(I) complexes of bridging bis(quinaldinyl)phenylphosphine oxide ligand. In: Phosphorus Sulfur and Silicon and the Related Elements, Bd. 195, Nr. 11: S. 918-923

Abstract

A novel tertiary phosphine oxide containing two quinaldinyl substituents has been synthesized according to adapted literature procedures. Its coordination properties toward Cu(I) and Ag(I) were investigated and the resulting complexes were analyzed by single crystal X-ray diffraction. Multinuclear complexes are formed, wherein the ligand is bridging across two metal centers. Though for the silver complex, no argentophilic interactions are present. The copper complex was characterized further by multinuclear NMR spectroscopy at variable temperatures.

• Dokumententyp: Zeitschriftenartikel
• Fakultät: Chemie und Pharmazie > Department Chemie
• Themengebiete: 500 Naturwissenschaften und Mathematik > 540 Chemie
• ISSN: 1042-6507
• Sprache: Englisch