Nucleophilic Reactivities of Thiophenolates

Justel, Patrick M.; Pignot, Cedric D. und Ofial, Armin R. (2021): Nucleophilic Reactivities of Thiophenolates. In: Journal of Organic Chemistry, Bd. 86, Nr. 8: S. 5965-5972

Abstract

The nucleophilic reactivities of substituted thiophenolates were determined by following the kinetics of their reactions with a series of quinone methides (reference electrophiles) in DMSO at 20 degrees C. The experimentally determined second-order rate constants were analyzed according to the Mayr-Patz equation log k = s(N)(N + E) to derive the nucleophile-specific reactivity parameters N and sN for ten thiophenolate ions.

• Dokumententyp: Zeitschriftenartikel
• Fakultät: Chemie und Pharmazie > Department Chemie
• Themengebiete: 500 Naturwissenschaften und Mathematik > 540 Chemie
• ISSN: 0022-3263
• Sprache: Englisch