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Koehler, Victor; Gauthier, Maxime; Yao, Chenhao; Fournel-Marotte, Karine; Waeles, Philip; Kauffmann, Brice; Huc, Ivan; Coutrot, Frederic und Ferrand, Yann (2022): [3]Foldarotaxane-mediated synthesis of an improbable [2]rotaxane. In: Chemical Communications, Bd. 58, Nr. 62: S. 8618-8621

Volltext auf 'Open Access LMU' nicht verfügbar.

Abstract

The wrapping of an aromatic oligoamide helix around an active ester-containing [2]rotaxane enforced the sliding and the sequestration of the surrounding macrocycle around a part of the axle for which it has no formal affinity. The foldamer-mediated compartmentalization of the [2]rotaxane shuttle was subsequently used to prepare an improbable rotaxane.

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