Abstract
Single crystals of Al1-xGaxPO4 of various mole fractions x were grown from phosphoric acid solutions under hydrothermal conditions using the slow-heating method. In order to relate the parameters of this low-quartz structure analogue and the observed phase transitions to the respective mole fraction, the crystals were investigated by means of electron probe microanalysis, X-ray powder diffraction and differential thermal analysis. The results are discussed in terms of the segregation effects occuring during growth. The limiting geometrical parameters for the existence of the high-quartz phase are compared to the values given in the literature.
Item Type: | Journal article |
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Faculties: | Geosciences > Department of Earth and Environmental Sciences > Crystallography and Materials Science |
Subjects: | 500 Science > 550 Earth sciences and geology |
Language: | English |
Item ID: | 18466 |
Date Deposited: | 10. Mar 2014, 14:08 |
Last Modified: | 04. Nov 2020, 13:00 |