Abstract
A new willemite-type compound, [(Li, Na, H)0.16Zn 1.92SiO4)] was synthesized from both solid-state reactions and molten NaCl. X-ray single crystal and neutron powder diffraction studies indicate the presence of Li+, Na+, and H+ in four and six membered-ring channels of alternately arranged ZnO4 and SiO4. The presence of channel cations is new to among numerous willemite-variants reported so far. This new configuration is attributed to defects at the Zn-sites. The new willemite-type material can be regarded as a prototype for combined cationic conductors.
| Item Type: | Journal article |
|---|---|
| Faculties: | Geosciences > Department of Earth and Environmental Sciences > Crystallography and Materials Science |
| Subjects: | 500 Science > 550 Earth sciences and geology |
| Language: | English |
| Item ID: | 18795 |
| Date Deposited: | 10. Mar 2014 14:14 |
| Last Modified: | 04. Nov 2020 13:00 |
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