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Wang, Jinhua; Wicher, Barbara; Maurizot, Victor; Huc, Ivan (2020): Oligo-Quinolylene-Vinylene Foldamers. In: Chemistry-A European Journal, Vol. 27, No. 3: pp. 1031-1038
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Abstract

Quinoline based aromatic amide foldamers are known to adopt stable folded conformations. We have developed a synthetic approach to produce similar oligomers where all amide bonds, or part of them, have been replaced by an isosteric vinylene group. The results of solution and solid state structural studies show that oligomers exclusively containing vinylene linkages are not well folded, and adopt predominantly flat conformations. In contrast, a vinylene segment flanked by helical oligoamides also folds in a helix, albeit with a slightly lower curvature. The presence of vinylene functions also result in an extension of pi-conjugation across the oligomer that may change charge transport properties. Altogether, these results pave the way to foldamers in which both structural control and specific electronic properties may be engineered.