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Veröffentlichungsdatum
Anzahl der Publikationen: 52
2024
Mousavi, Mohammad S.; Di Mola, Antonia; Pierri, Giovanni; Tedesco, Consiglia; Hensinger, Magenta J.; Sun, Aijia; Wang, Yilan; Mayer, Peter 
ORCID: https://orcid.org/0000-0002-1847-8032; Ofial, Armin R. ORCID: https://orcid.org/0000-0002-9600-2793 und Massa, Antonio
(30. April 2024):
Lactone Enolates of Isochroman-3-ones and 2‑Coumaranones: Quantification of Their Nucleophilicity in DMSO and Conjugate Additions to Chalcones.
In: Journal of Organic Chemistry, Bd. 89, Nr. 10: S. 6915-6928
[PDF, 2MB]
ORCID: https://orcid.org/0000-0002-1847-8032; Ofial, Armin R. ORCID: https://orcid.org/0000-0002-9600-2793 und Massa, Antonio
(30. April 2024):
Lactone Enolates of Isochroman-3-ones and 2‑Coumaranones: Quantification of Their Nucleophilicity in DMSO and Conjugate Additions to Chalcones.
In: Journal of Organic Chemistry, Bd. 89, Nr. 10: S. 6915-6928
[PDF, 2MB]
Timofeeva, Daria S. ORCID: https://orcid.org/0000-0002-9667-3669; Puente, Ángel ORCID: https://orcid.org/0000-0002-5593-1895; Ofial, Armin R. ORCID: https://orcid.org/0000-0002-9600-2793 und Mayr, Herbert ORCID: https://orcid.org/0000-0003-0768-5199
(2024):
Reactivity of Electrophilic Trifluoromethylating Reagents.
In: European Journal of Organic Chemistry, Bd. 27, Nr. 13
[PDF, 4MB]
ORCID: https://orcid.org/0000-0002-9667-3669; Puente, Ángel ORCID: https://orcid.org/0000-0002-5593-1895; Ofial, Armin R. ORCID: https://orcid.org/0000-0002-9600-2793 und Mayr, Herbert ORCID: https://orcid.org/0000-0003-0768-5199
(2024):
Reactivity of Electrophilic Trifluoromethylating Reagents.
In: European Journal of Organic Chemistry, Bd. 27, Nr. 13
[PDF, 4MB]
Hensinger, Magenta J.; Eitzinger, Andreas; Trapp, Oliver ORCID: https://orcid.org/0000-0002-3594-5181 und Ofial, Armin R. ORCID: https://orcid.org/0000-0002-9600-2793
(2024):
Nucleophilicity of 4-(Alkylthio)-3-imidazoline Derived Enamines.
In: Chemistry - A European Journal, Bd. 30, Nr. 2, e202302764
[PDF, 6MB]
ORCID: https://orcid.org/0000-0002-3594-5181 und Ofial, Armin R. ORCID: https://orcid.org/0000-0002-9600-2793
(2024):
Nucleophilicity of 4-(Alkylthio)-3-imidazoline Derived Enamines.
In: Chemistry - A European Journal, Bd. 30, Nr. 2, e202302764
[PDF, 6MB]
2023
Eitzinger, Andreas; Reitz, Justus; Antoni, Patrick W.; Mayr, Herbert ORCID: https://orcid.org/0000-0003-0768-5199; Ofial, Armin R. ORCID: https://orcid.org/0000-0002-9600-2793 und Hansmann, Max M.
(29. August 2023):
Pushing the Upper Limit of Nucleophilicity Scales by Mesoionic N-Heterocyclic Olefins.
In: Angewandte Chemie International Edition, Bd. 62, Nr. 40, e202309790
[PDF, 6MB]
ORCID: https://orcid.org/0000-0003-0768-5199; Ofial, Armin R. ORCID: https://orcid.org/0000-0002-9600-2793 und Hansmann, Max M.
(29. August 2023):
Pushing the Upper Limit of Nucleophilicity Scales by Mesoionic N-Heterocyclic Olefins.
In: Angewandte Chemie International Edition, Bd. 62, Nr. 40, e202309790
[PDF, 6MB]
Hensinger, Magenta J.; Closs, Anna C.; Trapp, Oliver ORCID: https://orcid.org/0000-0002-3594-5181 und Ofial, Armin R. ORCID: https://orcid.org/0000-0002-9600-2793
(9. Juni 2023):
The effect of S-alkylation on organocatalytic enamine activation through imidazolidine-4-thiones.
In: Chemical Communications
[PDF, 969kB]
ORCID: https://orcid.org/0000-0002-3594-5181 und Ofial, Armin R. ORCID: https://orcid.org/0000-0002-9600-2793
(9. Juni 2023):
The effect of S-alkylation on organocatalytic enamine activation through imidazolidine-4-thiones.
In: Chemical Communications
[PDF, 969kB]
Eitzinger, Andreas und Ofial, Armin R. ORCID: https://orcid.org/0000-0002-9600-2793
(25. April 2023):
Reactivity of electrophilic cyclopropanes.
In: Pure and Applied Chemistry, Bd. 95, Nr. 4: S. 389-400
[PDF, 1MB]
ORCID: https://orcid.org/0000-0002-9600-2793
(25. April 2023):
Reactivity of electrophilic cyclopropanes.
In: Pure and Applied Chemistry, Bd. 95, Nr. 4: S. 389-400
[PDF, 1MB]
Li, Le; Hsu, Jer-Ray; Zhao, Hongqing und Ofial, Armin R. ORCID: https://orcid.org/0000-0002-9600-2793
(26. Januar 2023):
Nucleophilicities of Cyclic α-Diazo Carbonyl Compounds.
In: European Journal of Organic Chemistry, Bd. 26, Nr. 10, e202300005
[PDF, 4MB]
ORCID: https://orcid.org/0000-0002-9600-2793
(26. Januar 2023):
Nucleophilicities of Cyclic α-Diazo Carbonyl Compounds.
In: European Journal of Organic Chemistry, Bd. 26, Nr. 10, e202300005
[PDF, 4MB]
Mayr, Herbert ORCID: https://orcid.org/0000-0003-0768-5199 und Ofial, Armin R. ORCID: https://orcid.org/0000-0002-9600-2793
(2023):
When Does Hammond's Postulate Predict Stabilities of Carbocations?
In: Israel Journal of Chemistry, Bd. 63, Nr. 7-8
[PDF, 5MB]
ORCID: https://orcid.org/0000-0003-0768-5199 und Ofial, Armin R. ORCID: https://orcid.org/0000-0002-9600-2793
(2023):
When Does Hammond's Postulate Predict Stabilities of Carbocations?
In: Israel Journal of Chemistry, Bd. 63, Nr. 7-8
[PDF, 5MB]
2022
An, Feng; Jangra, Harish; Wei, Yin; Shi, Min; Zipse, Hendrik und Ofial, Armin R. ORCID: https://orcid.org/0000-0002-9600-2793
(21. Februar 2022):
Reactivities of allenic and olefinic Michael acceptors towards phosphines.
In: Chemical Communications, Bd. 58, Nr. 20: S. 3358-3361
[PDF, 3MB]
ORCID: https://orcid.org/0000-0002-9600-2793
(21. Februar 2022):
Reactivities of allenic and olefinic Michael acceptors towards phosphines.
In: Chemical Communications, Bd. 58, Nr. 20: S. 3358-3361
[PDF, 3MB]
Li, Le; Mayer, Peter; Stephenson, David S.; Ofial, Armin R.; Mayer, Robert J. und Mayr, Herbert
(2022):
An Overlooked Pathway in 1,3-Dipolar Cycloadditions of Diazoalkanes with Enamines.
In: Angewandte Chemie International Edition, Bd. 61, Nr. 12
[PDF, 4MB]
Traube, Franziska R.; Bras, Natercia F.; Roos, Wynand P.; Sommermann, Corinna C.; Diehl, Tamara; Mayer, Robert J.; Ofial, Armin R.; Müller, Markus; Zipse, Hendrik und Carell, Thomas
(2022):
Epigenetic Anti-Cancer Treatment With a Stabilized Carbocyclic Decitabine Analogue.
In: Chemistry - A European Journal, Bd. 28, Nr. 26
[PDF, 3MB]
Li, Le; Mayer, Robert J.; Stephenson, David S.; Mayer, Peter; Ofial, Armin R. und Mayr, Herbert
(2022):
Quantification of the Electrophilicities of Diazoalkanes: Kinetics and Mechanism of Azo Couplings with Enamines and Sulfonium Ylides.
In: Chemistry - A European Journal, Bd. 28, Nr. 55
[PDF, 12MB]
Li, Le; Mayer, Peter; Ofial, Armin R. und Mayr, Herbert
(2022):
Cyclobutane Formation by the Reaction of Ethenesulfonyl Fluoride with Dimethyl Diazomalonate.
In: European Journal of Organic Chemistry, Bd. 2022, Nr. 39
[PDF, 5MB]
Jüstel, Patrick M. ORCID: https://orcid.org/0000-0002-1857-5916; Rovó, Petra ORCID: https://orcid.org/0000-0001-8729-7326; Mayr, Herbert ORCID: https://orcid.org/0000-0003-0768-5199 und Ofial, Armin R. ORCID: https://orcid.org/0000-0002-9600-2793
(2022):
Dynamics of the dimethyl sulfide exchange of (1,3‐diphenylallyl)dimethylsulfonium ions.
In: Journal of Physical Organic Chemistry, Bd. 35, Nr. 11
[PDF, 2MB]
ORCID: https://orcid.org/0000-0002-1857-5916; Rovó, Petra ORCID: https://orcid.org/0000-0001-8729-7326; Mayr, Herbert ORCID: https://orcid.org/0000-0003-0768-5199 und Ofial, Armin R. ORCID: https://orcid.org/0000-0002-9600-2793
(2022):
Dynamics of the dimethyl sulfide exchange of (1,3‐diphenylallyl)dimethylsulfonium ions.
In: Journal of Physical Organic Chemistry, Bd. 35, Nr. 11
[PDF, 2MB]
Mayer, Robert J.; Hampel, Nathalie; Ofial, Armin R. und Mayr, Herbert
(2022):
Resolving the Mechanistic Complexity in Triarylborane-Induced Conjugate Additions.
In: ACS Catalysis, Bd. 12, Nr. 24: S. 15298-15309
Macchia, Antonio; Summa, Francesco F.; Monaco, Guglielmo; Eitzinger, Andreas; Ofial, Armin R.; Di Mola, Antonia und Massa, Antonio
(2022):
Access to beta-Alkylated beta-Functionalized Ketones via Conjugate Additions to Arylideneisoxazol-5-ones and Mo(CO)(6)-Mediated Reductive Cascade Reactions.
In: ACS Omega, Bd. 7, Nr. 10: S. 8808-8818
Hartnagel, Manfred; Ofial, Armin R. und Mayr, Herbert
(2022):
Elucidation of the Nucleophilic Potential of Diazocyclopentadiene.
In: Synthesis, Bd. 55, Nr. 2: S. 354-358
2021
Micheletti, Gabriele; Mayer, Robert J.; Cino, Silvia; Boga, Carla; Mazzanti, Andrea; Ofial, Armin R. und Mayr, Herbert
(2021):
Quantification of the Lewis Basicities and Nucleophilicities of 1,3,5-Tris(dialkylamino)benzenes.
In: European Journal of Organic Chemistry, Bd. 2021, Nr. 46: S. 6347-6357
Mayer, Robert J.; Hampel, Nathalie und Ofial, Armin R.
(2021):
Lewis Acidic Boranes, Lewis Bases, and Equilibrium Constants: A Reliable Scaffold for a Quantitative Lewis Acidity/Basicity Scale.
In: Chemistry-A European Journal, Bd. 27, Nr. 12: S. 4070-4080
Mayer, Robert J.; Allihn, Patrick W. A.; Hampel, Nathalie; Mayer, Peter; Sieber, Stephan A. und Ofial, Armin R.
(2021):
Electrophilic reactivities of cyclic enones and alpha,beta-unsaturated lactones.
In: Chemical Science, Bd. 12, Nr. 13: S. 4850-4865
Maji, Biplab; Duan, Xin-Hua; Juestel, Patrick M.; Byrne, Peter A.; Ofial, Armin R. und Mayr, Herbert
(2021):
Nucleophilicities and Nucleofugalities of Thio- and Selenoethers.
In: Chemistry - A European Journal, Bd. 27, Nr. 44: S. 11367-11376
Macchia, Antonio; Summa, Francesco F.; Di Mola, Antonia; Tedesco, Consiglia; Pierri, Giovanni; Ofial, Armin R.; Monaco, Guglielmo und Massa, Antonio
(2021):
Base-Promoted Cascade Reactions for the Synthesis of 3,3-Dialkylated Isoindolin-1-ones and 3-Methyleneisoindolin-1-ones.
In: Journal of Organic Chemistry, Bd. 86, Nr. 21: S. 15128-15138
Justel, Patrick M.; Stan, Alexandra; Pignot, Cedric D. und Ofial, Armin R.
(2021):
Inherent Reactivity of Spiro-Activated Electrophilic Cyclopropanes.
In: Chemistry-A European Journal, Bd. 27, Nr. 64: S. 15928-15935
Justel, Patrick M.; Pignot, Cedric D. und Ofial, Armin R.
(2021):
Nucleophilic Reactivities of Thiophenolates.
In: Journal of Organic Chemistry, Bd. 86, Nr. 8: S. 5965-5972
2020
Mayer, Robert J.; Ofial, Armin R.; Mayr, Herbert und Legault, Claude Y.
(2020):
Lewis Acidity Scale of Diaryliodonium Ions toward Oxygen, Nitrogen, and Halogen Lewis Bases.
In: Journal of the American Chemical Society, Bd. 142, Nr. 11: S. 5221-5233
An, Feng; Maji, Biplab; Min, Elizabeth; Ofial, Armin R. und Mayr, Herbert
(2020):
Basicities and Nucleophilicities of Pyrrolidines and Imidazolidinones Used as Organocatalysts.
In: Journal of the American Chemical Society, Bd. 142, Nr. 3: S. 1526-1547
Li, Zhen; Mayer, Robert J.; Ofial, Armin R. und Mayr, Herbert
(2020):
From Carbodiimides to Carbon Dioxide: Quantification of the Electrophilic Reactivities of Heteroallenes.
In: Journal of the American Chemical Society, Bd. 142, Nr. 18: S. 8383-8402
Eitzinger, Andreas; Mayer, Robert J.; Hampel, Nathalie; Mayer, Peter; Waser, Mario und Ofial, Armin R.
(2020):
Electrophilic Reactivities of Vinyl p-Quinone Methides.
In: Organic Letters, Bd. 22, Nr. 6: S. 2182-2186
Winter, Michael; Schütz, Roman; Eitzinger, Andreas; Ofial, Armin R. und Waser, Mario
(2020):
CF3-Containing para-Quinone Methides for Organic Synthesis.
In: European Journal of Organic Chemistry, Bd. 2020, Nr. 25: S. 3812-3817
Zhang, Jingjing; Chen, Quan; Mayer, Robert J.; Yang, Jin-Dong; Ofial, Armin R.; Cheng, Jin-Pei und Mayr, Herbert
(2020):
Predicting Absolute Rate Constants for Huisgen Reactions of Unsaturated Iminium Ions with Diazoalkanes.
In: Angewandte Chemie-International Edition, Bd. 59, Nr. 30: S. 12527-12533
[PDF, 1MB]
2019
Mayer, Robert J.; Hampel, Nathalie; Mayer, Peter; Ofial, Armin R. und Mayr, Herbert
(2019):
Synthesis, Structure, and Properties of Amino-Substituted Benzhydrylium Ions - A Link between Ordinary Carbocations and Neutral Electrophiles.
In: European Journal of Organic Chemistry, Bd. 2019, Nr. 2-3: S. 412-421
Timofeeva, Dada S.; Ofial, Armin R. und Mayr, Herbert
(2019):
Nucleophilic reactivities of Schiff base derivatives of amino acids.
In: Tetrahedron, Bd. 75, Nr. 4: S. 459-463
Leonov, Artem I.; Timofeeva, Daria S.; Ofial, Armin R. und Mayr, Herbert
(2019):
Metal Enolates - Enamines - Enol Ethers: How Do Enolate Equivalents Differ in Nucleophilic Reactivity?
In: Synthesis-Stuttgart, Bd. 51, Nr. 5: S. 1157-1170
Mayer, Robert J.; Breugst, Martin; Hampel, Nathalie; Ofial, Armin R. und Mayr, Herbert
(2019):
Ambident Reactivity of Phenolate Anions Revisited: A Quantitative Approach to Phenolate Reactivities.
In: Journal of Organic Chemistry, Bd. 84, Nr. 14: S. 8837-8858
Mayer, Robert J. und Ofial, Armin R.
(2019):
Nucleophilicity of Glutathione: A Link to Michael Acceptor Reactivities.
In: Angewandte Chemie-international Edition, Bd. 58, Nr. 49: S. 17704-17708
[PDF, 2MB]
2018
Timofeeva, Dania S.; Ofial, Armin R. und Mayr, Herbert
(2018):
Kinetics of Electrophilic Fluorinations of Enamines and Carbanions: Comparison of the Fluorinating Power of N-F Reagents.
In: Journal of the American Chemical Society, Bd. 140, Nr. 36: S. 11474-11486
Jangra, Harish; Chen, Quan; Fuks, Elina; Zenz, Ivo; Mayer, Peter; Ofial, Armin R.; Zipse, Hendrik und Mayr, Herbert
(2018):
Nucleophilicity and Electrophilicity Parameters for Predicting Absolute Rate Constants of Highly Asynchronous 1,3-Dipolar Cycloadditions of Aryldiazomethanes.
In: Journal of the American Chemical Society, Bd. 140, Nr. 48: S. 16758-16772
Mayer, Robert J. und Ofial, Armin R.
(2018):
Intramolecular Hydrogen-Bonding Modulates the Nucleophilic Reactivity of Ammonium-Peroxycarboxylates.
In: European Journal of Organic Chemistry, Nr. 43: S. 6010-6017
Li, Zhen; Jangra, Harish; Chen, Quan; Mayer, Peter; Ofial, Armin R.; Zipse, Hendrik und Mayr, Herbert
(2018):
Kinetics and Mechanism of Oxirane Formation by Darzens Condensation of Ketones: Quantification of the Electrophilicities of Ketones.
In: Journal of the American Chemical Society, Bd. 140, Nr. 16: S. 5500-5515
Mayer, Robert J. und Ofial, Armin R.
(2018):
Nucleophilic Reactivities of Bleach Reagents.
In: Organic Letters, Bd. 20, Nr. 10: S. 2816-2820
Levens, Alison; An, Feng; Fernando, Jared E. M.; Ofial, Armin R.; Lupton, David W. und Mayr, Herbert
(2018):
Quantification of the Michael-Acceptor Reactivity of alpha,beta-Unsaturated Acyl Azolium Ions.
In: Topics in Catalysis, Bd. 61, Nr. 7-8: S. 585-590
Timofeeva, Daria S.; Mayer, Robert J.; Mayer, Peter; Ofial, Armin R. und Mayr, Herbert
(2018):
Which Factors Control the Nucleophilic Reactivities of Enamines?
In: Chemistry-A European Journal, Bd. 24, Nr. 22: S. 5901-5910
2017
Puente, Ángel; Ofial, Armin R. und Mayr, Herbert
(2017):
Nucleophilic Reactivities of Bis-Acceptor-Substituted Benzyl Anions.
In: European Journal of Organic Chemistry, Nr. 8: S. 1196-1202
Follet, Elsa; Mayer, Peter; Stephenson, David S.; Ofial, Armin R. und Berionni, Guillaume
(2017):
Reactivity-Tuning in Frustrated Lewis Pairs: Nucleophilicity and Lewis Basicity of Sterically Hindered Phosphines.
In: Chemistry-A European Journal, Bd. 23, Nr. 31: S. 7422-7427
Mayr, Herbert und Ofial, Armin R.
(2017):
Philicity, fugality, and equilibrium constants: when do rate-equilibrium relationships break down?
In: Pure and Applied Chemistry, Bd. 89, Nr. 6: S. 729-744
Follet, Elsa; Zipse, Hendrik; Lakhdar, Sami; Ofial, Armin R. und Berionni, Guillaume
(2017):
Nucleophilicities and Lewis Basicities of Sterically Hindered Pyridines.
In: Synthesis-Stuttgart, Bd. 49, Nr. 15: S. 3495-3504
Mayer, Robert J.; Tokuyasu, Takahiro; Mayer, Peter; Gomar, Jerome; Sabelle, Stephane; Mennucci, Benedetta; Mayr, Herbert und Ofial, Armin R.
(2017):
Solvation Accounts for the Counterintuitive Nucleophilicity Ordering of Peroxide Anions.
In: Angewandte Chemie-international Edition, Bd. 56, Nr. 43: S. 13279-13282
Allgäuer, Dominik S.; Jangra, Harish; Asahara, Haruyasu; Li, Zhen; Chen, Quan; Zipse, Hendrik; Ofial, Armin R. und Mayr, Herbert
(2017):
Quantification and Theoretical Analysis of the Electrophilicities of Michael Acceptors.
In: Journal of the American Chemical Society, Bd. 139, Nr. 38: S. 13318-13329
2016
Mayr, Herbert und Ofial, Armin R.
(2016):
Philicities, Fugalities, and Equilibrium Constants.
In: Accounts of Chemical Research, Bd. 49, Nr. 5: S. 952-965
Puente, Ángel; He, Shanshan; Corral-Bautista, Francisco; Ofial, Armin R. und Mayr, Herbert
(2016):
Nucleophilic Reactivities of 2-Substituted Malonates.
In: European Journal of Organic Chemistry, Nr. 10: S. 1841-1848
Chelli, Saloua; Troshin, Konstantin; Mayer, Peter; Lakhdar, Sami; Ofial, Armin R. und Mayr, Herbert
(2016):
Nucleophilicity Parameters of Stabilized Iodonium Ylides for Characterizing Their Synthetic Potential.
In: Journal of the American Chemical Society, Bd. 138, Nr. 32: S. 10304-10313
2011
Schriever, Christian; Lochbrunner, Stefan; Ofial, Armin R. und Riedle, Eberhard ORCID: https://orcid.org/0000-0002-2672-5718
(Februar 2011):
The origin of ultrafast proton transfer: Multidimensional wave packet motion vs. tunneling.
In: Chemical Physics Letters, Bd. 503, Nr. 1-3: S. 61-65
ORCID: https://orcid.org/0000-0002-2672-5718
(Februar 2011):
The origin of ultrafast proton transfer: Multidimensional wave packet motion vs. tunneling.
In: Chemical Physics Letters, Bd. 503, Nr. 1-3: S. 61-65