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Anzahl der Publikationen: 179
2024
Timofeeva, Daria S. 
ORCID: https://orcid.org/0000-0002-9667-3669; Puente, Ángel ORCID: https://orcid.org/0000-0002-5593-1895; Ofial, Armin R. ORCID: https://orcid.org/0000-0002-9600-2793 und Mayr, Herbert ORCID: https://orcid.org/0000-0003-0768-5199
(2024):
Reactivity of Electrophilic Trifluoromethylating Reagents.
In: European Journal of Organic Chemistry, Bd. 27, Nr. 13
[PDF, 4MB]
ORCID: https://orcid.org/0000-0002-9667-3669; Puente, Ángel ORCID: https://orcid.org/0000-0002-5593-1895; Ofial, Armin R. ORCID: https://orcid.org/0000-0002-9600-2793 und Mayr, Herbert ORCID: https://orcid.org/0000-0003-0768-5199
(2024):
Reactivity of Electrophilic Trifluoromethylating Reagents.
In: European Journal of Organic Chemistry, Bd. 27, Nr. 13
[PDF, 4MB]
2023
Eitzinger, Andreas; Reitz, Justus; Antoni, Patrick W.; Mayr, Herbert ORCID: https://orcid.org/0000-0003-0768-5199; Ofial, Armin R. ORCID: https://orcid.org/0000-0002-9600-2793 und Hansmann, Max M.
(29. August 2023):
Pushing the Upper Limit of Nucleophilicity Scales by Mesoionic N-Heterocyclic Olefins.
In: Angewandte Chemie International Edition, Bd. 62, Nr. 40, e202309790
[PDF, 6MB]
ORCID: https://orcid.org/0000-0003-0768-5199; Ofial, Armin R. ORCID: https://orcid.org/0000-0002-9600-2793 und Hansmann, Max M.
(29. August 2023):
Pushing the Upper Limit of Nucleophilicity Scales by Mesoionic N-Heterocyclic Olefins.
In: Angewandte Chemie International Edition, Bd. 62, Nr. 40, e202309790
[PDF, 6MB]
Mayr, Herbert ORCID: https://orcid.org/0000-0003-0768-5199 und Ofial, Armin R. ORCID: https://orcid.org/0000-0002-9600-2793
(2023):
When Does Hammond's Postulate Predict Stabilities of Carbocations?
In: Israel Journal of Chemistry, Bd. 63, Nr. 7-8
[PDF, 5MB]
ORCID: https://orcid.org/0000-0003-0768-5199 und Ofial, Armin R. ORCID: https://orcid.org/0000-0002-9600-2793
(2023):
When Does Hammond's Postulate Predict Stabilities of Carbocations?
In: Israel Journal of Chemistry, Bd. 63, Nr. 7-8
[PDF, 5MB]
2022
Li, Le; Mayer, Peter; Ofial, Armin R. und Mayr, Herbert
(2022):
Cyclobutane Formation by the Reaction of Ethenesulfonyl Fluoride with Dimethyl Diazomalonate.
In: European Journal of Organic Chemistry, Bd. 2022, Nr. 39
[PDF, 5MB]
Li, Le; Mayer, Robert J.; Stephenson, David S.; Mayer, Peter; Ofial, Armin R. und Mayr, Herbert
(2022):
Quantification of the Electrophilicities of Diazoalkanes: Kinetics and Mechanism of Azo Couplings with Enamines and Sulfonium Ylides.
In: Chemistry - A European Journal, Bd. 28, Nr. 55
[PDF, 12MB]
Li, Le; Mayer, Peter; Stephenson, David S.; Ofial, Armin R.; Mayer, Robert J. und Mayr, Herbert
(2022):
An Overlooked Pathway in 1,3-Dipolar Cycloadditions of Diazoalkanes with Enamines.
In: Angewandte Chemie International Edition, Bd. 61, Nr. 12
[PDF, 4MB]
Jüstel, Patrick M. ORCID: https://orcid.org/0000-0002-1857-5916; Rovó, Petra ORCID: https://orcid.org/0000-0001-8729-7326; Mayr, Herbert ORCID: https://orcid.org/0000-0003-0768-5199 und Ofial, Armin R. ORCID: https://orcid.org/0000-0002-9600-2793
(2022):
Dynamics of the dimethyl sulfide exchange of (1,3‐diphenylallyl)dimethylsulfonium ions.
In: Journal of Physical Organic Chemistry, Bd. 35, Nr. 11
[PDF, 2MB]
ORCID: https://orcid.org/0000-0002-1857-5916; Rovó, Petra ORCID: https://orcid.org/0000-0001-8729-7326; Mayr, Herbert ORCID: https://orcid.org/0000-0003-0768-5199 und Ofial, Armin R. ORCID: https://orcid.org/0000-0002-9600-2793
(2022):
Dynamics of the dimethyl sulfide exchange of (1,3‐diphenylallyl)dimethylsulfonium ions.
In: Journal of Physical Organic Chemistry, Bd. 35, Nr. 11
[PDF, 2MB]
Mayer, Robert J.; Hampel, Nathalie; Ofial, Armin R. und Mayr, Herbert
(2022):
Resolving the Mechanistic Complexity in Triarylborane-Induced Conjugate Additions.
In: ACS Catalysis, Bd. 12, Nr. 24: S. 15298-15309
Hartnagel, Manfred; Ofial, Armin R. und Mayr, Herbert
(2022):
Elucidation of the Nucleophilic Potential of Diazocyclopentadiene.
In: Synthesis, Bd. 55, Nr. 2: S. 354-358
Perrin, Charles L.; Agranat, Israel; Bagno, Alessandro; Braslavsky, Silvia E.; Fernandes, Pedro Alexandrino; Gal, Jean-Francois; Lloyd-Jones, Guy C.; Mayr, Herbert; Murdoch, Joseph R.; Nudelman, Norma Sbarbati; Radom, Leo; Rappoport, Zvi; Ruasse, Marie-Francoise; Siehl, Hans-Ullrich; Takeuchi, Yoshito; Tidwell, Thomas T.; Uggerud, Einar und Williams, Ian H.
(2022):
Glossary of terms used in physical organic chemistry (IUPAC Recommendations 2021).
In: Pure and Applied Chemistry, Bd. 94, Nr. 4: S. 353-534
2021
Micheletti, Gabriele; Mayer, Robert J.; Cino, Silvia; Boga, Carla; Mazzanti, Andrea; Ofial, Armin R. und Mayr, Herbert
(2021):
Quantification of the Lewis Basicities and Nucleophilicities of 1,3,5-Tris(dialkylamino)benzenes.
In: European Journal of Organic Chemistry, Bd. 2021, Nr. 46: S. 6347-6357
Maji, Biplab; Duan, Xin-Hua; Juestel, Patrick M.; Byrne, Peter A.; Ofial, Armin R. und Mayr, Herbert
(2021):
Nucleophilicities and Nucleofugalities of Thio- and Selenoethers.
In: Chemistry - A European Journal, Bd. 27, Nr. 44: S. 11367-11376
2020
An, Feng; Maji, Biplab; Min, Elizabeth; Ofial, Armin R. und Mayr, Herbert
(2020):
Basicities and Nucleophilicities of Pyrrolidines and Imidazolidinones Used as Organocatalysts.
In: Journal of the American Chemical Society, Bd. 142, Nr. 3: S. 1526-1547
Mayer, Robert J.; Ofial, Armin R.; Mayr, Herbert und Legault, Claude Y.
(2020):
Lewis Acidity Scale of Diaryliodonium Ions toward Oxygen, Nitrogen, and Halogen Lewis Bases.
In: Journal of the American Chemical Society, Bd. 142, Nr. 11: S. 5221-5233
Zhang, Jingjing; Chen, Quan; Mayer, Robert J.; Yang, Jin-Dong; Ofial, Armin R.; Cheng, Jin-Pei und Mayr, Herbert
(2020):
Predicting Absolute Rate Constants for Huisgen Reactions of Unsaturated Iminium Ions with Diazoalkanes.
In: Angewandte Chemie-International Edition, Bd. 59, Nr. 30: S. 12527-12533
[PDF, 1MB]
Li, Zhen; Mayer, Robert J.; Ofial, Armin R. und Mayr, Herbert
(2020):
From Carbodiimides to Carbon Dioxide: Quantification of the Electrophilic Reactivities of Heteroallenes.
In: Journal of the American Chemical Society, Bd. 142, Nr. 18: S. 8383-8402
2019
Mayer, Robert J.; Breugst, Martin; Hampel, Nathalie; Ofial, Armin R. und Mayr, Herbert
(2019):
Ambident Reactivity of Phenolate Anions Revisited: A Quantitative Approach to Phenolate Reactivities.
In: Journal of Organic Chemistry, Bd. 84, Nr. 14: S. 8837-8858
Hussein, Mohanad A.; Tran, Uyen P. N.; Huynh, Vien T.; Ho, Junming; Bhadbhade, Mohan; Mayr, Herbert und Nguyen, Thanh V.
(2019):
Halide Anion Triggered Reactions of Michael Acceptors with Tropylium Ion.
In: Angewandte Chemie-International Edition, Bd. 59, Nr. 4: S. 1455-1459
Leonov, Artem I.; Timofeeva, Daria S.; Ofial, Armin R. und Mayr, Herbert
(2019):
Metal Enolates - Enamines - Enol Ethers: How Do Enolate Equivalents Differ in Nucleophilic Reactivity?
In: Synthesis-Stuttgart, Bd. 51, Nr. 5: S. 1157-1170
Timofeeva, Dada S.; Ofial, Armin R. und Mayr, Herbert
(2019):
Nucleophilic reactivities of Schiff base derivatives of amino acids.
In: Tetrahedron, Bd. 75, Nr. 4: S. 459-463
Mayer, Robert J.; Hampel, Nathalie; Mayer, Peter; Ofial, Armin R. und Mayr, Herbert
(2019):
Synthesis, Structure, and Properties of Amino-Substituted Benzhydrylium Ions - A Link between Ordinary Carbocations and Neutral Electrophiles.
In: European Journal of Organic Chemistry, Bd. 2019, Nr. 2-3: S. 412-421
2018
Jangra, Harish; Chen, Quan; Fuks, Elina; Zenz, Ivo; Mayer, Peter; Ofial, Armin R.; Zipse, Hendrik und Mayr, Herbert
(2018):
Nucleophilicity and Electrophilicity Parameters for Predicting Absolute Rate Constants of Highly Asynchronous 1,3-Dipolar Cycloadditions of Aryldiazomethanes.
In: Journal of the American Chemical Society, Bd. 140, Nr. 48: S. 16758-16772
Zhang, Jingjing; Yang, Jin-Dong; Zheng, Hanliang; Xue, Xiao-Song; Mayr, Herbert und Cheng, Jin-Pei
(2018):
Exploration of the Synthetic Potential of Electrophilic Trifluoromethylthiolating and Difluoromethylthiolating Reagents.
In: Angewandte Chemie-International Edition, Bd. 57, Nr. 39: S. 12690-12695
Li, Zhen; Jangra, Harish; Chen, Quan; Mayer, Peter; Ofial, Armin R.; Zipse, Hendrik und Mayr, Herbert
(2018):
Kinetics and Mechanism of Oxirane Formation by Darzens Condensation of Ketones: Quantification of the Electrophilicities of Ketones.
In: Journal of the American Chemical Society, Bd. 140, Nr. 16: S. 5500-5515
Timofeeva, Dania S.; Ofial, Armin R. und Mayr, Herbert
(2018):
Kinetics of Electrophilic Fluorinations of Enamines and Carbanions: Comparison of the Fluorinating Power of N-F Reagents.
In: Journal of the American Chemical Society, Bd. 140, Nr. 36: S. 11474-11486
Levens, Alison; An, Feng; Fernando, Jared E. M.; Ofial, Armin R.; Lupton, David W. und Mayr, Herbert
(2018):
Quantification of the Michael-Acceptor Reactivity of alpha,beta-Unsaturated Acyl Azolium Ions.
In: Topics in Catalysis, Bd. 61, Nr. 7-8: S. 585-590
Timofeeva, Daria S.; Mayer, Robert J.; Mayer, Peter; Ofial, Armin R. und Mayr, Herbert
(2018):
Which Factors Control the Nucleophilic Reactivities of Enamines?
In: Chemistry-A European Journal, Bd. 24, Nr. 22: S. 5901-5910
2017
Puente, Ángel; Ofial, Armin R. und Mayr, Herbert
(2017):
Nucleophilic Reactivities of Bis-Acceptor-Substituted Benzyl Anions.
In: European Journal of Organic Chemistry, Nr. 8: S. 1196-1202
Byrne, Peter A.; Kobayashi, Shinjiro; Würthwein, Ernst-Ulrich; Ammer, Johannes und Mayr, Herbert
(2017):
Why Are Vinyl Cations Sluggish Electrophiles?
In: Journal of the American Chemical Society, Bd. 139, Nr. 4: S. 1499-1511
Mayr, Herbert und Ofial, Armin R.
(2017):
Philicity, fugality, and equilibrium constants: when do rate-equilibrium relationships break down?
In: Pure and Applied Chemistry, Bd. 89, Nr. 6: S. 729-744
Mayer, Robert J.; Tokuyasu, Takahiro; Mayer, Peter; Gomar, Jerome; Sabelle, Stephane; Mennucci, Benedetta; Mayr, Herbert und Ofial, Armin R.
(2017):
Solvation Accounts for the Counterintuitive Nucleophilicity Ordering of Peroxide Anions.
In: Angewandte Chemie-international Edition, Bd. 56, Nr. 43: S. 13279-13282
Garcia-Ruiz, Cristina; Chen, Jack L.-Y.; Sandford, Christopher; Feeney, Kathryn; Lorenzo, Paula; Berionni, Guillaume; Mayr, Herbert und Aggarwal, Varinder K.
(2017):
Stereospecific Allylic Functionalization: The Reactions of Allylboronate Complexes with Electrophiles.
In: Journal of the American Chemical Society, Bd. 139, Nr. 43: S. 15324-15327
Li, Zhen; Chen, Quan; Mayer, Peter und Mayr, Herbert
(2017):
Nucleophilicity Parameters of Arylsulfonyl-Substituted Halomethyl Anions.
In: Journal of Organic Chemistry, Bd. 82, Nr. 4: S. 2011-2017
Allgäuer, Dominik S.; Jangra, Harish; Asahara, Haruyasu; Li, Zhen; Chen, Quan; Zipse, Hendrik; Ofial, Armin R. und Mayr, Herbert
(2017):
Quantification and Theoretical Analysis of the Electrophilicities of Michael Acceptors.
In: Journal of the American Chemical Society, Bd. 139, Nr. 38: S. 13318-13329
2016
Chelli, Saloua; Troshin, Konstantin; Lakhdar, Sami; Mayr, Herbert und Mayer, Peter
(2016):
Crystal structure of 2-[chloro(4-methoxyphenyl)-methyl]-2-(4-methoxyphenyl)-5,5-dimethylcyclohexane-1,3-dione.
In: Acta Crystallographica Section E - Crystallographic Communications, Bd. 72:
300-+
[PDF, 728kB]
Berionni, Guillaume; Kurouchi, Hiroaki; Eisenburger, Lucien und Mayr, Herbert
(2016):
Nucleophilicity of Alkyl Zirconocene and Titanocene Precatalysts, and Kinetics of Activation by Carbenium Ions and by B(C6F5)(3).
In: Chemistry-A European Journal, Bd. 22, Nr. 32: S. 11196-11200
Chelli, Saloua; Troshin, Konstantin; Lakhdar, Sami; Mayr, Herbert und Mayer, Peter
(2016):
Crystal structure of (1S, 2R)-6,6-dimethyl-4,8-dioxo-2-phenylspiro[2.5] octane-1-carbaldehyde.
In: Acta Crystallographica Section E-Crystallographic Communications, Bd. 72:
266-+
[PDF, 464kB]
Mayr, Herbert und Ofial, Armin R.
(2016):
Philicities, Fugalities, and Equilibrium Constants.
In: Accounts of Chemical Research, Bd. 49, Nr. 5: S. 952-965
Levens, Alison; An, Feng; Breugst, Martin; Mayr, Herbert und Lupton, David W.
(2016):
Influence of the N-Substituents on the Nucleophilicity and Lewis Basicity of N-Heterocyclic Carbenes.
In: Organic Letters, Bd. 18, Nr. 15: S. 3566-3569
Chelli, Saloua; Troshin, Konstantin; Mayer, Peter; Lakhdar, Sami; Ofial, Armin R. und Mayr, Herbert
(2016):
Nucleophilicity Parameters of Stabilized Iodonium Ylides for Characterizing Their Synthetic Potential.
In: Journal of the American Chemical Society, Bd. 138, Nr. 32: S. 10304-10313
Nathel, Noah F. Fine; Morrill, Lucas A.; Mayr, Herbert und Garg, Neil K.
(2016):
Quantification of the Electrophilicity of Benzyne and Related Intermediates.
In: Journal of the American Chemical Society, Bd. 138, Nr. 33: S. 10402-10405
Zhang, Zhe; Puente, Ángel; Wang, Fang; Rahm, Martin; Mei, Yuncai; Mayr, Herbert und Prakash, G. K. Surya
(2016):
The Nucleophilicity of Persistent -Monofluoromethide Anions.
In: Angewandte Chemie-international Edition, Bd. 55, Nr. 41: S. 12845-12849
Chen, Quan; Mayer, Peter und Mayr, Herbert
(2016):
Ethenesulfonyl Fluoride: The Most Perfect Michael Acceptor Ever Found?
In: Angewandte Chemie-international Edition, Bd. 55, Nr. 41: S. 12664-12667
Mayr, Herbert
(2016):
Physical Organic Chemistry-Development and Perspectives.
In: Israel Journal of Chemistry, Bd. 56, Nr. 1: S. 30-37
Follet, Elsa; Mayer, Peter und Mayr, Herbert
(2016):
Lewis Acidities of Indol-3-ylmethylium Ions and Intrinsic Barriers of Their Reactions with Phosphines and Pyridines.
In: European Journal of Organic Chemistry, Nr. 23: S. 4050-4058
Puente, Ángel; He, Shanshan; Corral-Bautista, Francisco; Ofial, Armin R. und Mayr, Herbert
(2016):
Nucleophilic Reactivities of 2-Substituted Malonates.
In: European Journal of Organic Chemistry, Nr. 10: S. 1841-1848
Byrne, Peter A.; Karaghiosoff, Konstantin und Mayr, Herbert
(2016):
Ambident Reactivity of Acetyl- and Formyl-Stabilized Phosphonium Ylides.
In: Journal of the American Chemical Society, Bd. 138, Nr. 35: S. 11272-11281
2012
Lakhdar, Sami; Baidya, Mahiuddin und Mayr, Herbert
(2012):
Kinetics and mechanism of organocatalytic aza-Michael additions: direct observation of enamine intermediates.
In: Chemical Communications, Bd. 48, Nr. 37: S. 4504-4506
[PDF, 919kB]
2011
Lakhdar, Sami und Mayr, Herbert
(2011):
Counterion effects in iminium-activated electrophilic aromatic substitutions of pyrroles.
In: Chemical Communications, Bd. 47, Nr. 6: S. 1866-1868
[PDF, 623kB]
Duan, Xin-Hua; Maji, Biplab und Mayr, Herbert
(2011):
Characterization of the nucleophilic reactivities of thiocarboxylate, dithiocarbonate and dithiocarbamate anions.
In: Organic & Biomolecular Chemistry, Bd. 9: S. 8046-8050
[PDF, 297kB]
2010
Sailer, Christian F.; Fingerhut, Benjamin P.; Ammer, Johannes; Nolte, Christoph; Pugliesi, Igor; Mayr, Herbert; Vivie-Riedle, Regina de und Riedle, Eberhard ORCID: https://orcid.org/0000-0002-2672-5718
(2010):
The First Picoseconds in the Life of Benzhydryl Cations: Ultrafast Generation and Chemical Reactions.
International Conference on Ultrafast Phenomena, Snowmass, Colorado, United States, 18–23 July 2010.
Technical Digest.
Optical Society of America.
ORCID: https://orcid.org/0000-0002-2672-5718
(2010):
The First Picoseconds in the Life of Benzhydryl Cations: Ultrafast Generation and Chemical Reactions.
International Conference on Ultrafast Phenomena, Snowmass, Colorado, United States, 18–23 July 2010.
Technical Digest.
Optical Society of America.
2008
Schaller, Heike F.; Schmidhammer, Uli; Riedle, Eberhard ORCID: https://orcid.org/0000-0002-2672-5718 und Mayr, Herbert
(2008):
Ambident reactivity of the cyanate anion.
In: Chemistry - A European Journal, Bd. 14, Nr. 13: S. 3866-3868
ORCID: https://orcid.org/0000-0002-2672-5718 und Mayr, Herbert
(2008):
Ambident reactivity of the cyanate anion.
In: Chemistry - A European Journal, Bd. 14, Nr. 13: S. 3866-3868
2007
Baidya, Mahiuddin; Kobayashi, Shinjiro; Brotzel, Frank; Schmidhammer, Uli; Riedle, Eberhard ORCID: https://orcid.org/0000-0002-2672-5718 und Mayr, Herbert
(August 2007):
DABCO oder DMAP – worauf beruht ihr Unterschied in der Organokatalyse?
In: Angewandte Chemie, Bd. 119, Nr. 32: S. 6288-6292
ORCID: https://orcid.org/0000-0002-2672-5718 und Mayr, Herbert
(August 2007):
DABCO oder DMAP – worauf beruht ihr Unterschied in der Organokatalyse?
In: Angewandte Chemie, Bd. 119, Nr. 32: S. 6288-6292
Baidya, Mahiuddin; Kobayashi, Shinjiro; Brotzel, Frank; Schmidhammer, Uli; Riedle, Eberhard ORCID: https://orcid.org/0000-0002-2672-5718 und Mayr, Herbert
(2007):
DABCO and DMAP - Why are they different in organocatalysis?
In: Angewandte Chemie International Edition, Bd. 46, Nr. 32: S. 6176-6179
ORCID: https://orcid.org/0000-0002-2672-5718 und Mayr, Herbert
(2007):
DABCO and DMAP - Why are they different in organocatalysis?
In: Angewandte Chemie International Edition, Bd. 46, Nr. 32: S. 6176-6179
2005
Tishkov, Alexander A.; Schmidhammer, Uli; Roth, Stefan; Riedle, Eberhard ORCID: https://orcid.org/0000-0002-2672-5718 und Mayr, Herbert
(Juli 2005):
Die ambidente Reaktivität von Nitrit‐Ionen neu aufgerollt.
In: Angewandte Chemie, Bd. 117, Nr. 29: S. 4699-4703
ORCID: https://orcid.org/0000-0002-2672-5718 und Mayr, Herbert
(Juli 2005):
Die ambidente Reaktivität von Nitrit‐Ionen neu aufgerollt.
In: Angewandte Chemie, Bd. 117, Nr. 29: S. 4699-4703
1994
Mayr, Herbert; Gorath, Gorden und Bauer, Bernhard
(1994):
Flüssiges Schwefeldioxid als Lewis-acides Solvens für die Alkylierung und Alkoxyalkylierung von Allylsilanen.
In: Angewandte Chemie, Bd. 106, Nr. 7: S. 793-794
[PDF, 2MB]
Mayr, Herbert und Patz, Matthias
(1994):
Nucleophilie- und Elektrophilieskalen als Ordnungsprinzipien polarer organischer und metallorganischer Reaktionen.
In: Angewandte Chemie, Bd. 106, Nr. 9: S. 990-1010
[PDF, 9MB]
Dau-Schmidt, Jan-Peter und Mayr, Herbert
(1994):
Relative Reactivities of Alkyl Chlorides under Friedel-Crafts Conditions.
In: Chemische Berichte, Bd. 127, Nr. 1: S. 205-212
[PDF, 2MB]
Mayr, Herbert und Dau-Schmidt, Jan-Peter
(1994):
Relative Reactivities of Acetals and Ethers under Friedel-Crafts Conditions.
In: Chemische Berichte, Bd. 127, Nr. 1: S. 213-217
[PDF, 1MB]
Mayr, Herbert; Gonzalez, Jose L. und Lüdtke, Kerstin
(1994):
Comparison of the Nucleophilicities of Alkynes and Alkenes. Quantitative Determination of the Nucleophilicities of Alkynes toward Carbenium Ions.
In: Chemische Berichte, Bd. 127, Nr. 3: S. 525-531
[PDF, 1MB]
Mayr, Herbert und Rau, Doris
(1994):
How Electrophilic are Ferrocenylmethyl Cations? Kinetics of their Reactions with Nucleophiles and Hydride Donors.
In: Chemische Berichte, Bd. 127, Nr. 12: S. 2493-2498
[PDF, 1MB]
Roth, Michael; Schade, Christian und Mayr, Herbert
(1994):
Kinetics of carbenium ion additions to methylenecycloalkanes. Cycloalkyl cation stabilities are not predominantly controlled by strain.
In: Journal of Organic Chemistry, Bd. 59, Nr. 1: S. 169-172
[PDF, 431kB]
Mayr, Herbert; Baran, Janusz; Will, Elfriede; Yamakoshi, Hideyuki; Teshima, Koichi und Nojima, Masatomo
(1994):
Exceptionally Stable Ozonides. Influence of Methyl Substituents on the Course of Cyclopentene Ozonolyses and on the Reactivities of Ozonides.
In: Journal of Organic Chemistry, Bd. 59, Nr. 17: S. 5055-5058
[PDF, 575kB]
Mayr, Herbert
(1994):
Nobelpreise 1994.
In: Chemie in unserer Zeit, Bd. 28, Nr. 6: S. 293-294
[PDF, 441kB]
1993
Patz, Matthias und Mayr, Herbert
(1993):
How nucleophilic are silyl enol ethers? Kinetics of the reactions of electron rich CC-double bonded systems with carbenium ions.
In: Tetrahedron Letters, Bd. 34, Nr. 21: S. 3393-3396
[PDF, 248kB]
Basso, Nils; Goers, Solvig; Popowski, Eckhard und Mayr, Herbert
(1993):
Hyperconjugative stabilization of silicenium ions: kinetics of hydride abstractions from .beta.-element-substituted silanes.
In: Journal of the American Chemical Society, Bd. 115, Nr. 14: S. 6025-6028
[PDF, 425kB]
Mayr, Herbert; Heigl, Ulrich W. und Baran, Janusz
(1993):
A Stepwise [4 + 3] Cycloaddition Reaction of the 1,3-Diphenyl-2-azaallyl Anion.
In: Chemische Berichte, Bd. 126, Nr. 8: S. 1913-1916
[PDF, 1MB]
1992
Mayr, Herbert; Bäuml, Englbert; Cibura, Gerlinde und Koschinsky, Rainer
(1992):
Synthesis of cyclopentenes via [3 + 2]-cycloadditions of silylated propargyl .tautm. allenyl cations with alkenes.
In: Journal of Organic Chemistry, Bd. 57, Nr. 2: S. 768-772
[PDF, 721kB]
Mayr, Herbert und Grimm, Klaus
(1992):
Synthesis of allylazo compounds by reactions of aryldiazonium salts with allylsilanes.
In: Journal of Organic Chemistry, Bd. 57, Nr. 2: S. 1057-1059
[PDF, 313kB]
Mayr, Herbert; Basso, Nils und Hagen, Gisela
(1992):
Kinetics of hydride-transfer reactions from hydrosilanes to carbenium ions. Substituent effects in silicenium ions.
In: Journal of the American Chemical Society, Bd. 114, Nr. 8: S. 3060-3066
[PDF, 875kB]
Mayr, Herbert; Bartl, Joerg und Hagen, Gisela
(1992):
Geschwindigkeitskonstanten für den Angriff von Carbenium-Ionen an Arene - eine Brücke zwischen der Chemie aliphatischer und aromatischer -Systeme.
In: Angewandte Chemie, Bd. 104, Nr. 12: S. 1689-1691
[PDF, 2MB]
Mayr, Herbert und Basso, Nils
(1992):
Kinetik der Hydrid-Übertragungen von CH-, SiH-, GeH- und SnH-Gruppen auf Carbenium-Ionen.
In: Angewandte Chemie, Bd. 104, Nr. 8: S. 1103-1105
[PDF, 2MB]
Bentley, T. William; Dau-Schmidt, Jan-Peter; Llewellyn, Gareth und Mayr, Herbert
(1992):
Solvation effects adjacent to the reaction site. Differences in solvation between alkyl, alkenyl or alkynyl, and aryl groups in binary aqueous mixtures.
In: Journal of Organic Chemistry, Bd. 57, Nr. 8: S. 2387-2392
[PDF, 708kB]
1991
Hagen, Gisela und Mayr, Herbert
(1991):
Kinetics of the reactions of allylsilanes, allylgermanes, and allylstannanes with carbenium ions.
In: Journal of the American Chemical Society, Bd. 113, Nr. 13: S. 4954-4961
[PDF, 890kB]
Bartl, Joerg; Steenken, Steen und Mayr, Herbert
(1991):
Kinetics of the reactions of laser-flash photolytically generated carbenium ions with alkyl and silyl enol ethers. Comparison with the reactivity toward alkenes, allylsilanes and alcohols.
In: Journal of the American Chemical Society, Bd. 113, Nr. 20: S. 7710-7716
[PDF, 1MB]
Mayr, Herbert; Heilmann, Werner; Bäuml, Englbert und Vorbrüggen, Helmut
(1991):
Synthesis of 2,2,5,5-Tetramethylcyclopentanecarboxylic Acid. A Building Block of an Amino Acid Based Sweetener.
In: Chemische Berichte, Bd. 124, Nr. 1: S. 203-206
[PDF, 1MB]
Ohm, Stefan; Bäuml, Englbert und Mayr, Herbert
(1991):
A Versatile Synthesis of 1,4-Dienes. Use of Vinyl Ethers as Vinyl Cation Equivalents.
In: Chemische Berichte, Bd. 124, Nr. 12: S. 2785-2790
[PDF, 1MB]
Irrgang, Bernhard und Mayr, Herbert
(1991):
Additions of carbenium ions to nonconjugated dienes. The retarding (−I)-effect of the second double bond.
In: Tetrahedron, Bd. 47, Nr. 2: S. 219-228
[PDF, 640kB]
Mayr, Herbert; Baran, Janusz und Heigl, Ulrich W.
(1991):
3,3,4,4,5,5-Hexamethyl-1,2-bis(methylene)cyclopentane. A Novel Probe for the Study of Cycloaddition Mechanisms.
In: Gazzetta chimica italiana, Bd. 121, Nr. 8: S. 373-381
[PDF, 1MB]
1990
Musigmann, Klaus; Mayr, Herbert und Meijere, Armin de
(1990):
Regio- and stereoselective ring-opening reactions of cyclopropenones. α-methylene-γ-butyrolactones via additions of trichlorocyclopropenylium ions to alkenes.
In: Tetrahedron Letters, Bd. 31, Nr. 9: S. 1261-1264
[PDF, 231kB]
Mayr, Herbert; Schneider, Reinhard; Schade, Christian; Bartl, Joerg und Bederke, Rainer
(1990):
Addition reactions of diarylcarbenium ions to 2-methyl-1-pentene. kinetic method and reaction mechanism.
In: Journal of the American Chemical Society, Bd. 112, Nr. 11: S. 4446-4454
[PDF, 1MB]
Mayr, Herbert; Schneider, Reinhard; Irrgang, Bernhard und Schade, Christian
(1990):
Kinetics of the reactions of the p-methoxy-substituted benzhydryl cation with various alkenes and 1,3-dienes.
In: Journal of the American Chemical Society, Bd. 112, Nr. 11: S. 4454-4459
[PDF, 633kB]
Bartl, Joerg; Steenken, S.; Mayr, Herbert und McClelland, R. A.
(1990):
Photo-heterolysis and -homolysis of substituted diphenylmethyl halides, acetates, and phenyl ethers in acetonitrile: characterization of diphenylmethyl cations and radicals generated by 248-nm laser flash photolysis.
In: Journal of the American Chemical Society, Bd. 112, Nr. 19: S. 6918-6928
[PDF, 1MB]
Mayr, Herbert
(1990):
Knüpfung von CC-Bindungen durch Addition von Carbenium-Ionen an Alkene. Kinetik und Mechanismus.
In: Angewandte Chemie, Bd. 102, Nr. 12: S. 1415-1428
[PDF, 4MB]
Mayr, Herbert; Cambanis, Anton und Bäuml, Englbert
(1990):
Notizen/Notes Synthesis of -Oxo Esters from Silyl Enol Ethers and Dichlorobis(phenoxy)methane.
In: Chemische Berichte, Bd. 123, Nr. 7: S. 1571-1573
[PDF, 829kB]
Mayr, Herbert; Schneider, Reinhard und Grabis, Ute
(1990):
Linear free energy and reactivity-selectivity relationships in reactions of diarylcarbenium ions with .pi.-nucleophiles.
In: Journal of the American Chemical Society, Bd. 112, Nr. 11: S. 4460-4467
[PDF, 946kB]
1989
Mayr, Herbert und Hagen, Gisela
(1989):
Quantitative determination of the nucleophilicity of allylsilanes.
In: Journal of the Chemical Society, Chemical Communications: S. 91-92
[PDF, 168kB]
Baran, Janusz und Mayr, Herbert
(1989):
Mechanistic impact of oxime formation accompanying 1,3-dipolar cycloadditions of nitrile oxides.
In: Journal of Organic Chemistry, Bd. 54, Nr. 21: S. 5012-5016
[PDF, 626kB]
Baran, Janusz; Mayr, Herbert; Ruster, Volker und Klärner, Frank Gerrit
(1989):
Stepwise [4 + 2]- and [4 + 4]-cyclodimerizations of 1,1,2,2,3,3-hexamethyl-4,5-bis(methylene)cyclopentane.
In: Journal of Organic Chemistry, Bd. 54, Nr. 21: S. 5016-5019
[PDF, 501kB]
Baran, Janusz und Mayr, Herbert
(1989):
Competing [2 + 3] and [4 + 3] cycloadditions of C,N-diphenylnitrone with 1,3-dienes. Evidence for thermally nonequilibrated intermediates.
In: Journal of Organic Chemistry, Bd. 54, Nr. 24: S. 5774-5783
[PDF, 1MB]
Mayr, Herbert und Koschinsky, Rainer
(1989):
Stereoselective circumambulatory methyl migrations in the nonamethylcyclopentylium ion.
In: Journal of the American Chemical Society, Bd. 111, Nr. 6: S. 2305-2306
[PDF, 274kB]
Baran, Janusz und Mayr, Herbert
(1989):
Acceleration of diels-alder reactions by remote methyl groups.
In: Tetrahedron, Bd. 45, Nr. 11: S. 3347-3350
[PDF, 349kB]
Cambanis, Anton; Bäuml, Englbert und Mayr, Herbert
(1989):
Formylation of Allylsilanes. A Synthesis of β,γ-Unsaturated Aldehyde Acetals.
In: Synthesis: S. 128-129
[PDF, 186kB]
Mayr, Herbert
(1989):
Control of Electrophilicity in Aliphatic Friedel-Crafts Reactions.
In: Schinzer, D. (Hrsg.):
Selectivities in Lewis Acid Promoted Reactions. Dordrecht u.a.: Kluwer. S. 21-36
[PDF, 1MB]
1988
Koschinsky, Rainer; Köhli, Thies-Peter und Mayr, Herbert
(1988):
Synthesis of highly alkylated functionalized cyclopentadienes.
In: Tetrahedron Letters, Bd. 29, Nr. 44: S. 5641-5644
[PDF, 205kB]
Bäuml, Englbert; Tscheschlok, Kai; Pock, Rudolf und Mayr, Herbert
(1988):
Synthesis of γ-lactones from alkenes employing p-methoxybenzyl chloride as +CH2---CO−2 equivalent.
In: Tetrahedron Letters, Bd. 29, Nr. 52: S. 6925-6926
[PDF, 139kB]
Bentley, T. William; Irrgang, Bernhard; Mayr, Herbert und Schleyer, Paul v. R.
(1988):
Inductive effects in neighboring-group participation. Destabilization of carbocations by CC double bonds in solvolyses of 2,2,5,5-tetramethylcyclopent-3-en-1-yl tosylates.
In: Journal of Organic Chemistry, Bd. 53, Nr. 15: S. 3492-3498
[PDF, 1MB]
Brüggen, Uwe von der; Lammers, Roswitha und Mayr, Herbert
(1988):
Relative reactivities of acetals and orthoesters in Lewis acid catalyzed reactions with vinyl ethers. A systematic investigation of the synthetic potential of acetals and orthoesters in electrophilic alkoxyalkylations of enol ethers.
In: Journal of Organic Chemistry, Bd. 53, Nr. 13: S. 2920-2925
[PDF, 725kB]
Baran, Janusz und Mayr, Herbert
(1988):
Synthesis of hexamethylglutaric acid. an approach to compounds with adjacent quaternary carbon centers.
In: Journal of Organic Chemistry, Bd. 53, Nr. 19: S. 4626-4628
[PDF, 475kB]
Schade, Christian; Mayr, Herbert und Arnett, Edward M.
(1988):
Thermochemical study of the addition of carbenium ions to alkenes.
In: Journal of the American Chemical Society, Bd. 110, Nr. 2: S. 567-571
[PDF, 682kB]
Brüggen, Uwe von der und Mayr, Herbert
(1988):
Comment of the use of dichloromethyl methyl ether as formylating agent.
In: Chemische Berichte, Bd. 121, Nr. 1: S. 191-193
[PDF, 607kB]
Mayr, Herbert und Brüggen, Uwe von der
(1988):
Electrophilic carboxylation of alkenes.
In: Chemische Berichte, Bd. 121, Nr. 2: S. 339-345
[PDF, 1MB]
Rahman, Azizur; Bäuml, Englbert; Klein, Herbert und Mayr, Herbert
(1988):
Prenylation of camphene. A carbocationic route to isosantalene and its derivatives.
In: Tetrahedron, Bd. 43, Nr. 18: S. 4119-4124
[PDF, 327kB]
Baran, Janusz; Klein, Herbert; Schade, Christian; Will, Elfriede; Koschinsky, Rainer; Bäuml, Englbert und Mayr, Herbert
(1988):
Synthesis of 1,1,2,2,3,3-hexamethyl-4,5-bis(methylene)cyclopentane.
In: Tetrahedron, Bd. 44, Nr. 8: S. 2181-2184
[PDF, 269kB]
Rahman, Azizur; Klein, Herbert; Dressel, Jürgen und Mayr, Herbert
(1988):
Diastereoselective synthesis of β- and γ2-muurolene. A carbocationic pathway from mono- to sesquiterpenes.
In: Tetrahedron, Bd. 44, Nr. 19: S. 6041-6045
[PDF, 354kB]
Heilmann, Werner; Rahman, Azizur; Bäuml, Englbert und Mayr, Herbert
(1988):
Carbocationic cyclisations and rearrangements in the damascone series.
In: Tetrahedron, Bd. 44, Nr. 19: S. 6047-6054
[PDF, 550kB]
Mayr, Herbert; Schneider, Reinhard und Schade, Christian
(1988):
Kinetic and Thermodynamic Studies of Carbenium Ion Additions Towards Alkenes.
In: Makromolekulare Chemie / Macromolecular Symposia, Bd. 13/14: S. 43-59
[PDF, 1MB]
Mayr, Herbert und Schade, Christian
(1988):
The role of chain transfer processes in inifer/boron trichloride initiated polymerizations of isobutene.
In: Die Makromolekulare Chemie, Rapid Communications, Bd. 9, Nr. 7: S. 483-488
[PDF, 253kB]
Schade, Christian und Mayr, Herbert
(1988):
Tritylium ions as initiators and co-initiators in cationic polymerizations.
In: Die Makromolekulare Chemie, Rapid Communications, Bd. 9, Nr. 7: S. 477-482
[PDF, 280kB]
Schade, Christian und Mayr, Herbert
(1988):
Solvolyses of diarylmethyl chlorides. A comprehensive stability scale for diarylcarbenium ions.
In: Tetrahedron, Bd. 44, Nr. 18: S. 5761-5770
[PDF, 714kB]
Cambanis, Anton; Bäuml, Englbert und Mayr, Herbert
(1988):
Synthesis of Bis(aryloxy)chloromethanes via Radical-Induced Chlorinations of Formaldehyde Diaryl Acetals.
In: Synthesis, Bd. 12: S. 961
[PDF, 98kB]
Mayr, Herbert; Cambanis, Anton und Bäuml, Englbert
(1988):
Synthesis of β,γ-Unsaturated Carboxylic Acid Esters via Aryloxycarbonylation of Allylsilanes.
In: Synthesis, Bd. 12: S. 962-963
[PDF, 160kB]
1987
Bäuml, Englbert; Kolberg, Gerlinde und Mayr, Herbert
(1987):
A carbocationic 1,3-alkenyl shift.
In: Tetrahedron Letters, Bd. 28, Nr. 4: S. 387-390
[PDF, 192kB]
Musigmann, Klaus; Mayr, Herbert und Meijere, Armin de
(1987):
Addition reactions of the trichlorocyclopropenylium ion with alkenes. A novel access to cyclopropene and cyclopropenone derivatives.
In: Tetrahedron Letters, Bd. 28, Nr. 39: S. 4517-4520
[PDF, 235kB]
Mayr, Herbert und Heigl, Ulrich W.
(1987):
[4 + 2] Cycloadditions of diphenylketene with a highly substituted 1,3-diene.
In: Journal of the Chemical Society, Chemical Communications: S. 1804-1805
[PDF, 135kB]
Mayr, Herbert; Koschinsky, Rainer; Will, Elfriede und Bäuml, Englbert
(1987):
Acid- and base-catalyzed ring-opening reactions or a sterically hindered epoxide.
In: Journal of Organic Chemistry, Bd. 52, Nr. 7: S. 1342-1344
[PDF, 474kB]
Heilmann, Werner; Koschinsky, Rainer und Mayr, Herbert
(1987):
The [3 + 2]- and [5 + 2]-cycloadditions of the cyclohepta-2,4-dienyl cation.
In: Journal of Organic Chemistry, Bd. 52, Nr. 10: S. 1989-1993
[PDF, 628kB]
Baran, Janusz und Mayr, Herbert
(1987):
First [4 + 3]-cycloaddition of a 1,3-dipole with a 1,3-diene.
In: Journal of the American Chemical Society, Bd. 109, Nr. 21: S. 6519-6521
[PDF, 367kB]
Mayr, Herbert; Schade, Christian; Rubow, Monika und Schneider, Reinhard
(1987):
Steuerung der relativen Elektrophilie von Alkylierungsmitteln durch Variation der Lewis-Säure-Konzentration.
In: Angewandte Chemie, Bd. 99, Nr. 10: S. 1059-1060
[PDF, 1MB]
Schneider, Ralf; Mayr, Herbert und Plesch, Peter H.
(1987):
Ionisation and Dissociation of Diarylmethyl Chlorides in BCl3/CH2Cl2 Solution. Spectroscopic Evidence for Carbenium Ion Pairs.
In: Berichte der Bunsengesellschaft / Physical Chemistry, Chemical Physics, Bd. 91: S. 1369-1374
[PDF, 2MB]
Heilmann, Werner; Mayr, Herbert und Vorbrüggen, Helmut
(1987):
Synthese von 2,2,5,5-Tetramethylcyclopentancarbonsäure: Baustein eines neuen Süßstoffs.
In: Focus MUL, Bd. 4, Nr. 2: S. 94-97
[PDF, 601kB]
1986
Schneider, Reinhard; Grabis, Ute und Mayr, Herbert
(1986):
Direkte Bestimmung der Additionsgeschwindigkeiten von Carbenium-Ionen an Alkene.
In: Angewandte Chemie, Bd. 98, Nr. 1: S. 94-95
[PDF, 1MB]
Schneider, Reinhard und Mayr, Herbert
(1986):
Direkte Messung der isokinetischen Geschwindigkeitskonstanten bei Additionen von Diarylcarbenium-Ionen an 2-Methyl-2-buten.
In: Angewandte Chemie, Bd. 98, Nr. 11: S. 1033-1034
[PDF, 1MB]
Mayr, Herbert; Schneider, Reinhard und Grabis, Ute
(1986):
Lineare Reaktivitäts-Selektivitäts-Korrelationen bei Additionen von Diarylcarbenium-Ionen an Alkene; eine Widerlegung des Reaktivitäts-Selektivitäts-Prinzips.
In: Angewandte Chemie, Bd. 98, Nr. 11: S. 1034-1036
[PDF, 1MB]
Pock, Rudolf; Klein, Herbert und Mayr, Herbert
(1986):
Elektrophile Alkylierungen von Norbornen - Synthese 7-substituierter Norbornene.
In: Chemische Berichte, Bd. 119, Nr. 3: S. 929-942
[PDF, 1MB]
Mayr, Herbert und Pock, Rudolf
(1986):
Relative Reaktivität Alkyl-substituierter Alkene und Cycloalkene gegenüber Diarylcarbenium-Ionen.
In: Chemische Berichte, Bd. 119, Nr. 8: S. 2473-2496
[PDF, 2MB]
Mayr, Herbert; Will, Elfriede; Heigl, Ulrich W. und Schade, Christian
(1986):
Bromination of octmethylcyclopentene. The irregular reactivity of a sterically hindered cycloalkene T.
In: Tetrahedron, Bd. 42, Nr. 9: S. 2519-2522
[PDF, 298kB]
Mayr, Herbert und Heilmann, Werner
(1986):
Steric control of regiochemistry in the reactions of methyl substituted pentadienyl cations with isobutene.
In: Tetrahedron, Bd. 42, Nr. 24: S. 6657-6662
[PDF, 413kB]
Mayr, Herbert; Hellman, Werner und Lammers, Roswitha
(1986):
A carbocationic route to 3-substituted 1,4-cycloheptadienes.
In: Tetrahedron, Bd. 42, Nr. 24: S. 6663-6668
[PDF, 365kB]
Mayr, Herbert; Schneider, Reinhard und Pock, Rudolf
(1986):
Addition Reactions of Carbocations with Alkenes. Studies on the Mechanism of Carbocationic Polymerization.
In: Makromolekulare Chemie / Macromolecular Symposia, Bd. 3: S. 19-31
[PDF, 1MB]
Mayr, Herbert und Pock, Rudolf
(1986):
Electrophilic attack at allylsilanes. A quantitative determination of the β-silyl effect.
In: Tetrahedron, Bd. 42, Nr. 15: S. 4211-4214
[PDF, 312kB]
Schleyer, Paul v. R.; Kaufmann, Elmar; Kos, Alexander J.; Mayr, Herbert und Chandrasekhar, Jayaraman
(1986):
Stabilization of the alleged bishomoromatic bicyclo[3.2.1]octa-2,6-dienyl anion by counterion interactions and by hyperconjugation.
In: Journal of the Chemical Society, Chemical Communications: S. 1583-1585
[PDF, 368kB]
Pock, Rudolf; Mayr, Herbert; Rubow, Monika und Wilhelm, Eberhard
(1986):
Do carbenium ion additions toward alkenes proceed via .pi. complexes? A stereochemical investigation.
In: Journal of the American Chemical Society, Bd. 108, Nr. 24: S. 7767-7772
[PDF, 775kB]
1985
Mayr, Herbert und Heigl, Ulrich W.
(1985):
1,4-Addition von Dihalogencarbenen an 1,3-Diene.
In: Angewandte Chemie, Bd. 97, Nr. 7: S. 567-568
[PDF, 475kB]
Mayr, Herbert und Striepe, Wilhelm
(1985):
Modification of the catalytic activity of zinc chloride. A kinetic investigation in zinc chloride-ether-dichloromethane mixtures.
In: Journal of Organic Chemistry, Bd. 50, Nr. 16: S. 2995-2998
[PDF, 537kB]
Bäuml, Englbert und Mayr, Herbert
(1985):
Silbertrifluoracetat-initiierte Reaktionen von Chlortriphenylallen mit Cyclopentadien - Vinylkation-analoge Cycloadditionen von Allenylkationen.
In: Chemische Berichte, Bd. 118, Nr. 2: S. 683-693
[PDF, 1MB]
Bäuml, Englbert und Mayr, Herbert
(1985):
Cycloadditionen des Triphenylallenyl-Kations mit Cyclopentadien. Studium des Reaktionsmechanismus unter stabilen Ionen-Bedingungen.
In: Chemische Berichte, Bd. 118, Nr. 2: S. 694-703
[PDF, 1MB]
Mayr, Herbert
(1985):
Von Paracelsus zum fünfbindigen Kohlenstoff. Der Einfluß der Carbokationen-Forschung auf die Strukturtheorie organischer Moleküle.
In: Focus MHL, Bd. 2: S. 211-221
Mayr, Herbert
(1985):
Elektrophile Alkylierungen von Alkenen.
In:
35 Jahre Fonds der chemischen Industrie 1950-1985. Frankfurt/Main: Verband der Chemischen Industrie. S. 111-118
[PDF, 744kB]
1984
Mayr, Herbert und Bäuml, Englbert
(1984):
[2+2]-cycloadditions of alkenes with the triphenylallenyl cation.
In: Tetrahedron Letters, Bd. 25, Nr. 11: S. 1127-1130
[PDF, 188kB]
Mayr, Herbert; Klein, Herbert und Kolberg, Gerlinde
(1984):
Lewis-Säure-katalysierte Additionen 1,3-Alkyl-substituierter Allylchloride an Alkene.
In: Chemische Berichte, Bd. 117, Nr. 8: S. 2555-2579
[PDF, 2MB]
Mayr, Herbert und Schneider, Reinhard
(1984):
The efficiency of alkyl halide initiators in carbocationic polymerization.
In: Die Makromolekulare Chemie, Rapid Communications, Bd. 5, Nr. 1: S. 43-46
[PDF, 194kB]
1983
Mayr, Herbert und Bäuml, Englbert
(1983):
Concerted [4+2] and stepwise [2+2]cycloadditions of the triphenylallenyl cation with cyclopentadiene.
In: Tetrahedron Letters, Bd. 24, Nr. 4: S. 357-360
[PDF, 183kB]
Mayr, Herbert und Pock, Rudolf
(1983):
Relative reactivities of alkenes toward the diphenylmethyl cation.
In: Tetrahedron Letters, Bd. 24, Nr. 21: S. 2155-2158
[PDF, 241kB]
Mayr, Herbert und Striepe, Wilhelm
(1983):
Scope and limitations of aliphatic Friedel-Crafts alkylations. Lewis acid catalyzed addition reactions of alkyl chlorides to carbon-carbon double bonds.
In: Journal of Organic Chemistry, Bd. 48, Nr. 8: S. 1159-1165
[PDF, 954kB]
Bäuml, Englbert und Mayr, Herbert
(1983):
Diels-Alder reactions of 2-alkynoyl chlorides with cyclopentadiene. a reinvestigation.
In: Journal of Organic Chemistry, Bd. 48, Nr. 15: S. 2600-2601
[PDF, 329kB]
Klein, Herbert; Freyberger, Gerhard und Mayr, Herbert
(1983):
[2+2]-Cycloadditionen von Allylkationen.
In: Angewandte Chemie, Bd. 95, Nr. 1: S. 62-63
[PDF, 442kB]
Mayr, Herbert; Klein, Herbert und Sippel, Elfriede
(1983):
Synthese von 1,2,3,3,6,6-Hexamethyl-1-cyclohexen. Eine Umlagerungskaskade von C12H23+-Kationen.
In: Chemische Berichte, Bd. 116, Nr. 11: S. 3624-3630
[PDF, 1MB]
1982
Klein, Herbert; Erbe, Anne und Mayr, Herbert
(1982):
Kationische Prenylierung von Olefinen.
In: Angewandte Chemie, Bd. 94, Nr. 1: S. 63
[PDF, 321kB]
Siehl, Hans Ullrich und Mayr, Herbert
(1982):
Stable vinyl cations. Direct spectroscopic observation of vinyl-substituted vinyl cations.
In: Journal of the American Chemical Society, Bd. 104, Nr. 3: S. 909-910
[PDF, 275kB]
Mayr, Herbert und Schneider, Reinhard
(1982):
Ab-initio-MO-Studie Methyl- und Phenyl-substituierter Allenyl-Kationen.
In: Chemische Berichte, Bd. 115, Nr. 10: S. 3470-3478
[PDF, 992kB]
Mayr, Herbert; Schütz, Franz und Halberstadt-Kausch, Inge K.
(1982):
Additions- und Cycloadditionsreaktionen von Allenyl-Kationen mit cyclischen 1,3-Dienen.
In: Chemische Berichte, Bd. 115, Nr. 11: S. 3516-3527
[PDF, 1MB]
Mayr, Herbert und Halberstadt-Kausch, Inge K.
(1982):
Cycloadditionsreaktionen von Allenyl-Kationen mit Cyclopentadien.
In: Chemische Berichte, Bd. 115, Nr. 11: S. 3479-3515
[PDF, 3MB]
Mayr, Herbert und Klein, Herbert
(1982):
Additions- und Cycloadditionsreaktionen von Allenyl-Kationen mit acyclischen 1,3-Dienen.
In: Chemische Berichte, Bd. 115, Nr. 11: S. 3528-3546
[PDF, 2MB]
1981
Mayr, Herbert und Schütz, Franz
(1981):
Addition and cycloaddition reactions of allenyl cations with various cycloalka-1,3-dienes.
In: Tetrahedron Letters, Bd. 22, Nr. 10: S. 925-928
[PDF, 264kB]
Mayr, Herbert
(1981):
Lewis-Säure-katalysierte Alkylierungen von CC-Mehrfachbindungen. Eine Möglichkeit zum gezielten Aufbau von Kohlenstoffgerüsten.
In: Angewandte Chemie, Bd. 93, Nr. 2: S. 202-204
[PDF, 672kB]
Klein, Herbert und Mayr, Herbert
(1981):
[3 + 2]-Cycloadditionen von Allylkationen - Synthese von Permethylcyclopenten und anderen hochsubstituierten Cyclopentenen.
In: Angewandte Chemie, Bd. 93, Nr. 12: S. 1069-1070
[PDF, 643kB]
Mayr, Herbert; Wilhelm, Eberhard und Kaliba, Claus
(1981):
[2 + 2]-Cycloaddition of a stabilised vinyl cation with cyclopentadiene; X-ray crystal structure of the 2 : 1 addition product.
In: Journal of the Chemical Society, Chemical Communications: S. 683-684
[PDF, 198kB]
Mayr, Herbert; Seitz, Brigitte und Halberstadt-Kausch, Inge K.
(1981):
Stepwise [2 + 2] and [3 + 2] "cycloaddition" reactions of allenyl cations with olefins.
In: Journal of Organic Chemistry, Bd. 46, Nr. 5: S. 1041-1043
[PDF, 375kB]
Mayr, Herbert und Klein, Herbert
(1981):
Zinc chloride catalyzed addition reactions of propargyl chlorides with acyclic 1,3-dienes.
In: Journal of Organic Chemistry, Bd. 46, Nr. 20: S. 4097-4100
[PDF, 471kB]
Mayr, Herbert; Schneider, Reinhard; Wilhelm, Dieter und Schleyer, Paul v. R.
(1981):
Vinyl cations. Comparison of gas-phase thermodynamic and solvolysis data with ab initio MO calculations.
In: Journal of Organic Chemistry, Bd. 46, Nr. 26: S. 5336-5340
[PDF, 604kB]
Kaufmann, Elmar; Mayr, Herbert; Chandrasekhar, Jayaraman und Schleyer, Paul v. R.
(1981):
Elusiveness of bishomoaromaticity in anionic systems: the bicyclo[3.2.1]octa-3,6-dien-2-yl anion.
In: Journal of the American Chemical Society, Bd. 103, Nr. 6: S. 1375-1380
[PDF, 701kB]
1980
Mayr, Herbert und Halberstadt, Inge K.
(1980):
Konkurrenz zwischen [3+4]- und [2+4]-Cycloadditionen von Allenylkationen.
In: Angewandte Chemie, Bd. 92, Nr. 10: S. 840-841
[PDF, 618kB]
1979
Mayr, Herbert; Grubmüller, Bärbel und Halberstadt, Inge K.
(1979):
Orientation effects in reactions of allenyl cations with styrene.
In: Tetrahedron Letters, Bd. 20, Nr. 20: S. 1749-1752
[PDF, 200kB]
Mayr, Herbert; Foerner, Wolfgang und Schleyer, Paul v. R.
(1979):
Methyl-substituted allyl cations. A comparison of experimental stability, rotational barrier, and solvolysis data with ab initio calculations.
In: Journal of the American Chemical Society, Bd. 101, Nr. 20: S. 6032-6040
[PDF, 913kB]
1978
Mayr, Herbert und Grubmüller, Bärbel
(1978):
[4 + 3]-Cycloadditionen von Allenylkationen.
In: Angewandte Chemie, Bd. 90, Nr. 2: S. 129-130
[PDF, 445kB]
Olah, George A.; Asensio, Gregorio und Mayr, Herbert
(1978):
Stable carbocations. 211. 1-Phenylallyl cations and their rearrangement to indanyl cations in superacidic media.
In: Journal of Organic Chemistry, Bd. 43, Nr. 8: S. 1518-1520
[PDF, 346kB]
Olah, George A.; Donovan, Daniel J.; Lin, Henry C.; Mayr, Herbert; Andreozzi, Patricia und Klopman, Gilles
(1978):
Onium ions. 18. Static protonated and exchanging diprotonated ambivalent heteroorganic systems. hydroxylamines, acetone oxime, and dimethyl sulfoxide.
In: Journal of Organic Chemistry, Bd. 43, Nr. 11: S. 2268-2272
[PDF, 590kB]
Olah, George A.; Asensio, Gregorio; Mayr, Herbert und Schleyer, Paul v. R.
(1978):
Carbanions. 3. Nuclear magnetic resonance spectroscopic and theoretical study of homoaromaticity in cyclohexadienyl anions.
In: Journal of the American Chemical Society, Bd. 100, Nr. 14: S. 4347-4352
[PDF, 683kB]
1977
Mayr, Herbert und Olah, George A.
(1977):
Stable carbocations. 202. Ring closure reactions of allyl to cyclopropylcarbinyl cations.
In: Journal of the American Chemical Society, Bd. 99, Nr. 2: S. 510-513
[PDF, 441kB]
1976
Huisgen, Rolf und Mayr, Herbert
(1976):
Reactions of cyclobutenones with nucleophilic reagents via vinylketen intermediates.
In: Journal of the Chemical Society, Chemical Communications, Nr. 2: S. 55-56
[PDF, 214kB]
Mayr, Herbert und Huisgen, Rolf
(1976):
Kinetics and mechanism of the conversion of cyclobutenones to vinylketens.
In: Journal Chemical Society, Chemical Communications: S. 57-58
[PDF, 191kB]
Olah, George A. und Mayr, Herbert
(1976):
Carbanions. II. Carbon-13 nuclear magnetic resonance study of Meisenheimer complexes and their charge distribution pattern.
In: Journal of Organic Chemistry, Bd. 41, Nr. 21: S. 3448-3451
[PDF, 561kB]
Olah, George A. und Mayr, Herbert
(1976):
Stable Carbocations. 198. Formation of Allyl Cations via Protonation of Alkynes in Magic Acid Solution. Evidence for 1,2-Hydrogen and Alkyl Shifts in the Intermediate Vinyl Cations.
In: Journal of the American Chemical Society, Bd. 98, Nr. 23: S. 7333-7340
[PDF, 880kB]
1975
Mayr, Herbert und Huisgen, Rolf
(1975):
Structural assignments of stereoisomeric cyclobutanones by substituent increments on chemical shifts.
In: Tetrahedron Letters, Bd. 16, Nr. 16: S. 1349-1352
[PDF, 199kB]
Huisgen, Rolf und Mayr, Herbert
(1975):
Kinetics of 2+2 cycloadditions of diphenylketene to enol ethers. The structure of the orientation complexes.
In: Tetrahedron Letters, Bd. 16, Nr. 34: S. 2965-2968
[PDF, 212kB]
Huisgen, Rolf und Mayr, Herbert
(1975):
Steric course, kinetics and mechanism of the 2+2 cycloadditions of alkylphenylketenes to ethyl - and -propenyl ether.
In: Tetrahedron Letters, Bd. 16, Nr. 34: S. 2969-2972
[PDF, 211kB]
Mayr, Herbert und Huisgen, Rolf
(1975):
Eine neue Synthese von Cyclobutenonen.
In: Angewandte Chemie, Bd. 87, Nr. 13: S. 491
[PDF, 303kB]
Mayr, Herbert
(1975):
Vinylketene aus Cyclobutenonen durch elektrocyclische Ringöffnung.
In: Angewandte Chemie, Bd. 87, Nr. 13: S. 491-492
[PDF, 468kB]